84107-76-6

Basic information

• Product Name: Benzenemethanol, a-[(2E)-3-phenyl-2-propenyl]-
• CAS NO: 84107-76-6
• Molecular Formula: C16H16O
• Molecular Weight: 224.302
• Mol File: 84107-76-6.mol
• Article Data: 34

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-[(2E)-3-phenyl-2-propenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-[(2E)-3-phenyl-2-propenyl]-(84107-76-6)
• EPA Substance Registry System: Benzenemethanol, a-[(2E)-3-phenyl-2-propenyl]-(84107-76-6)

Safety Data

• Hazardous Substances Data: 84107-76-6(Hazardous Substances Data)

Upstream product

• 84319-83-5 (E)-1,4-Diphenyl-2-(toluene-4-sulfonyl)-but-3-en-1-ol 
• 100-52-7 benzaldehyde 
• 4392-24-9 Cinnamyl bromide 
• 90766-67-9 1,1-dibromo-4-phenyl-1,3-butadiene 
• 14371-10-9 (E)-3-phenylpropenal 
• 4392-24-9 3-bromo-1-phenyl-1-propenyl bromide 
• 1743-36-8 1-phenylbut-3-yn-1-ol 
• 98-80-6 phenylboronic acid 
• 90364-78-6 phenyl (2-phenylcyclopropyl)-methanol 
• 1608-03-3 (E)-but-1-en-3-yn-1-ylbenzene 
• 13343-79-8 (E)-1,4-Diphenylbut-1-en-3-yne 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 74457-36-6 trans-1,4-diphenyl-4-methoxy-1-butene 
• 1616348-66-3 (E)-(4-fluorobut-1-ene-1,4-diyl)dibenzene 
• 100-52-7 benzaldehyde 
• 40395-23-1 3-phenyl-1-heptene 

Relevant articles and documents

Bismuth mediated barbier synthesis of α-homoallylic alcohols via a sigmatropic rearrangement in [bmim][HSO4]

A novel protocol for the Bismuth metal mediated regioselctive crotylation of aldehydes yielding α-homoallylic alcohols has been developed using 20mol% [bmim][HSO4] as a metal activator, as well as a mediator for regioconversion from the initially formed γ-regiomer. The present protocol minimizes the use of conventional solvents and proceeds with good yields and excellent regioselectivities.

Ni-Catalyzed regio- and stereoselective addition of arylboronic acids to terminal alkynes with a directing group tether

Addition of arylboronic acids to directing group tethered acetylenes in a regio and stereoselective manner using an inexpensive catalytic system is achieved for the first time to access highly sought after allyl/homoallyl alcohol/amine units. The apparent vinylnickel intermediate was successfully trapped by the Michael electrophiles to get defined tri- and tetra-substituted olefins. An interesting selectivity switch was observed with internal alkynes.

Hot water-promoted cyclopropylcarbinyl rearrangement facilitates construction of homoallylic alcohols

In refluxing 9 : 1 (v/v) H2O-1,4-dioxane and without an additional catalyst, the rearrangements of various types of cyclopropyl carbinols were attempted. It was found that the reactions generally gave homoallylic alcohols in good to very high chemical yields. Rearrangements of bicyclic or tricyclic cyclopropyl carbinols readily gave the desired ring-expanded cyclic homoallylic alcohols which are difficult to synthesize by other means.