74491-24-0Relevant academic research and scientific papers
A NEW FACILE METHOD FOR THE PREPARATION OF α-IMINONITRILES FROM ALDONITRONES AND CYANOTRIMETHYLSILANE.
Dutta, D. K.,Prajapati, D.,Sandhu, J. S.,Baruah, J. N.
, p. 335 - 340 (2007/10/02)
α-Iminonitriles have been obtained in good yields by reacting aldonitrones and cyanotrimethylsilane.
Une nouvelle methode de transformation des aldehydes aromatiques en α-iminonitriles Ar-C(CN)=N-R
Pochat, Francis
, p. 955 - 956 (2007/10/02)
The reaction with amines of bromoderivates Ar-CBr(SEt)-CN, easily obtained in high yields from aldehydes, provides a convinient route to C-aryl N-alkyl (or aryl) α-iminonitriles.
The Reaction between Cyanide Ion and Nitrones; a Novel Imidazole Synthesis
Cawkill, Eric,Clark, Nigel G.
, p. 244 - 248 (2007/10/02)
By contrast with the CN-diphenylnitrones, cold aqueous ethanolic potassium cyanide converts N-methyl-C-phenylnitrone into 1-methyl-4,5-diphenylimidazole.The scope of this reaction has been investigated, and shown to proceed via intermediate cyano-imines, some of which have been synthesised by alternative routes.
