74598-74-6

Basic information

• Product Name: Methanone, 1-cyclohexen-1-ylcyclohexyl-
• Synonyms: cyclohex-1-enyl-cyclohexyl ketone;Methanone,1-cyclohexen-1-ylcyclohexyl;Cyclohex-1-enyl-cyclohexyl-keton
• CAS NO: 74598-74-6
• Molecular Formula: C13H20O
• Molecular Weight: 192.301
• Mol File: 74598-74-6.mol
• Article Data: 9

Chemical Properties

• Melting Point: 176-177 °C
• Boiling Point: 152-153 °C(Press: 14 Torr)
• Density: 1.004±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Methanone, 1-cyclohexen-1-ylcyclohexyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, 1-cyclohexen-1-ylcyclohexyl-(74598-74-6)
• EPA Substance Registry System: Methanone, 1-cyclohexen-1-ylcyclohexyl-(74598-74-6)

Safety Data

• Hazardous Substances Data: 74598-74-6(Hazardous Substances Data)

Usage

Uses

Cyclohexyl-1-cyclohexenyl Ketone is used in the preparation of enones by nickel-catalyzed carbonylative Negishi cross-coupling.

Upstream product

• 60-29-7 diethyl ether 
• 36278-22-5 1-cyclohexenoyl chloride 
• 931-50-0 cyclohexylmagnesium bromide 
• 201230-82-2 carbon monoxide 
• 110-83-8 cyclohexene 
• 71-43-2 benzene 
• 108-94-1 cyclohexanone 
• 28075-50-5 cyclohex-1-en-1-yl trifluoromethane sulfonate 
• 931-51-1 cyclohexylmagnesiumchloride 
• 1977-87-3 cyclohexanecarbonyl fluoride 
• 102104-37-0 1-(Benzenesulfinyl-chloro-cyclohexyl-methyl)-cyclohexanol 
• 118096-73-4 7-(2-Phenylselenocyclohexylidene)bicyclo<4.1.0>heptane 
• 104354-60-1 cyclohexylchloromethyl phenyl sulfoxide 
• 83803-75-2 (1-chloro-cyclohexyl)-cyclohexyl ketone 

Downstream Products

• 129801-09-8 1-Cyclohexyl-1-(1,2-epoxycyclohexyl)ethylene 
• 107055-93-6 1-Hexahydrobenzoyl-2-dimethylamino-cyclohexan 
• 92792-98-8 1-Dimethylamino-dicyclohexylketon 

Relevant articles and documents

Enones from Acid Fluorides and Vinyl Triflates by Reductive Nickel Catalysis

A nickel-catalyzed reductive coupling between acid fluorides and vinyl triflates has been described. This method provides an efficient access to various enones and avoids the requirement for acyl or vinyl metallic reagents in the conventional approaches.

Some novel routes to 1-heterosubstituted 1-vinylcyclopropanes

3-Phenylselenoalk-1-enylidene carbenes, generated in situ by base induced condensation of α-phenylseleno carbonyl compounds and diethyl diazomethylphosphonate, can be efficiently trapped by alkenes to give alkylidene-cyclopropane adducts which undergo either [1,3] allyl selenide rearrangement or oxidative selenoxide [2,3] sigmatropic rearrangement to produce 1-phenylseleno- or 1-hydroxy-1-vinylcyclopropanes respectively.

Generation, Trapping, and Adduct Rearrangement of 3-Phenylselenoalk-1-enylidene Carbenes: a Novel Direct Route to 1-Hetero-substituted 1-Vinylcyclopropanes

3-Phenylselenoalk-1-enylidene carbenes, generated in situ by base-induced Horner-Wadsworth-Emmons condensation of α-phenylseleno carbonyl compounds and diethyl diazomethylphosphonate, may be efficiently trapped to give alkylidene-cyclopropane adducts which undergo either allyl selenide rearrangement or oxidative selenoxidesigmatropic rearrangement to produce 1-heterosubstituted 1-vinylcyclopropanes.