74710-80-8

Upstream product

• 3290-99-1 4-methoxybenzoic acid hydrazide 
• 67-64-1 acetone 

Downstream Products

• 15856-17-4 N-Isopropyl-N'-<4-methoxy-benzoyl>-hydrazin 
• 1260116-78-6 diethyl {1-[2-(4-methoxybenzoyl)hydrazino]-1-methylethyl}phosphonate 
• 58466-51-6 Co((CH₃)2CNNHC(O)C₆H₄OCH₃-p)2Cl₂ 
• 58466-52-7 Co((CH₃)2CNNHC(O)C₆H₄OCH₃-p)2(SCN)2 
• 63287-85-4 Ni(MBHA)2(NCS)2 
• 85846-51-1 2-methoxy-2-(4-methoxyphenyl)-5,5-dimethyl-Δ³-1,3,4-oxadiazoline 
• 85846-50-0 2-methoxy-2-(4-methoxyphenyl)-5,5-dimethyl-Δ³-1,3,4-oxadiazoline 

Relevant academic research and scientific papers

Effect of ligand substituents on supramolecular self-assembly and electrochemical properties of copper(II) complexes with benzoylhydrazones: X-ray crystal structures and cyclic voltammetry

Complexation of copper(II) with a series of hetero-donor chelating Schiff bases (HLLR) of para-substituted benzhydrazides (with R = OH, NO 2, CH3O, Cl and tert-butyl substituents) and acetone affords mononuclear [Cu(LLR)2] molecules: 1 [Cu(anbhz)2] (R = NO2); 2 [Cu(ahbhz)2] (R = OH) 3 [Cu(ambhz)2] (R = CH3O); 4 [Cu(acbhz)2] (R = Cl); and 5 [Cu(atbhz)2] (R = tert-butyl). Single-crystal X-ray diffraction results for 2-5 reveal their various supramolecular architectures including 1D and 2D dimensionalities. A detailed analysis of crystal structures allows to gain insight into intermolecular interactions accountable for self-assembly into different networks as well as for various physicochemical properties of the compounds. The major interactions include O-H...N hydrogen bonds (2) as well as CH...N and axial Cu...O (3); π...π stacking (4) and van der Waals CH...C interactions (5). All compounds are characterized by elemental analyses; IR and UV-Vis spectroscopy as well as magnetic susceptibility and cyclic voltammetry measurements. Electrochemical studies reveal the dependence of [Cu(LL R)2]/[Cu(LLR)2]- reduction potentials on substituents of benzoylhydrazonoate ligands.

Benzoylhydrazones in catalytic hydrophosphorylation

Reactions of benzoylhydrazones derived from heterocyclic and aromatic aldehydes and aliphatic, heterocyclic, and aliphatic-aromatic ketones with diethyl phosphite in the presence of [tetra(tert-butyl)phthalocyanine]aluminum chloride afford α-benzoylhydraz

An efficient synthesis of substituted hydrazides

Routes for the selective synthesis of 1-, or 2-substituted hydrazides, and 1,2-disubstituted hydrazides are reported. These routes proceed via cyanoborohydride reduction of stable acyl hydrazone intermediates. Georg Thieme Verlag Stuttgart.