74766-78-2

Upstream product

• 69982-70-3 3,4-di-O-acetyl-2,6-dibromo-2,6-dideoxy-5a-carba-β-DL-glucopyranosyl bromide 
• 24363-23-3 (+/-)-7-oxabicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid 
• 17791-32-1 7-Oxabicyclo<2.2.1>hept-5-en-2-carbonsaeure-methylester 
• 69982-68-9 endo-3-acetoxy-endo-5-acetoxymethyl-exo-2-bromo-7-oxabicyclo<2.2.1>heptane 

Downstream Products

• 80065-34-5 DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-bromomethyl-2-(toluene-p-sulfonamido)-1,3,4-cyclohexanetriol 
• 74766-79-3 DL-1,2-di-O-acetyl-(1,3/2)-3-benzoyloxymethyl-5-cyclohexene-1,2-diol 
• 74766-80-6 DL-1,2-di-O-acetyl-(1,3/2,4)-4-bromo-3-bromomethyl-5-cyclohexene-1,2-diol 
• 74780-33-9 DL-1,2-di-O-acetyl-(1,3/2,6)-3-bromo-6-bromomethyl-4-cyclohexene-1,2-diol 
• 74766-83-9 DL-1,2-di-O-acetyl-(1,4/2,3)-3,4-dibromo-6-bromomethyl-5-cyclohexene-1,2-diol 
• 74766-83-9 Acetic acid (1S,2R,5R,6R)-2-acetoxy-5,6-dibromo-3-bromomethyl-cyclohex-3-enyl ester 
• 99773-33-8 DL-trans-1,2-diacetoxy-3-methylene-5-cyclohexene 
• 80065-30-1 DL-trans-di-acetoxy-5-bromomethyl-2-cyclohexenone 
• 80065-31-2 DL-tetra-O-acetyl-(1,2,4/3,5)-5-bromomethyl-1,2,3,4-cyclohexanetetrol 
• 87661-88-9 DL-(1,3/2)-1,2-diacetoxy-3-acetoxymethyl-5-cyclohexene 
• 74766-85-1 trans-2,3-diacetoxy-1-[(benzoyloxy)methyl]-cyclohexa-4,6-diene 
• 74766-84-0 DL-1,2-di-O-acetyl-(1,6/2,5)-3-benzoyloxymethyl-5,6-dibromo-3-cyclohexene-1,2-diol 
• 17550-38-8 DL-3,4-di-O-acetyl-1,2-anhydro-(1,2/3,4)-2C-(benzoyloxymethyl)-5-cyclohexene-1,2,3,4-tetrol 
• 74766-86-2 D,L-(1,2,4/3)-3,4-di-O-acetyl-1,2-anhydro-5-benzoyloxymethyl-5-cyclohexene-1,2,3,4,-tetrol 

Relevant academic research and scientific papers

Synthesis of carba analogs of 6-O-(benzyl)-d-allal- and -d-galactal-derived allyl epoxides and evaluation of the regio- and stereoselective behavior in nucleophilic addition reactions

The new racemic diastereoisomeric epoxides 6α and 6β, the carba analogs of the corresponding d-galactal- and d-allal-derived allyl epoxides have been synthesized and their regio- and stereoselective behavior examined in addition reactions with model O-, C-, N-, and S-nucleophiles. The results have indicated that epoxide 6β has a pronounced tendency toward anti-1,2-addition, whereas epoxide 6α shows interesting levels of syn- and/or anti-1,4-addition processes. A chiral recognition process found with epoxide 6β, turned out to be consistently reduced in epoxide 6α. All the results have been rationalized on the basis of conformational, steric, and stereoelectronic effects.

Synthesis and glycosidase inhibitory activity of some N-substituted 5a-carba-β-fuco- and β-galactopyranosylamines, and selected derivatives

In the course of chemical modification of α-fucosidase inhibitors of 5a-carba-fucopyranosylamine type, an N-dodecyl derivative of the enantiomer 6-deoxy-5a-carba-β-d-galactopyranosylamine demonstrated very strong inhibition of β-galactosidase and β-glucos

Pseudo-sugars. VII. Synthesis of Pseudo-hexopyranose Derivatives with α- and β-Gluco Configurations

Several derivatives of pseudo-hexopyranose (5-hydroxymethyl-1,2,3,4-cyclohexanetetrol) with α-gluco, (1,2,4/3,5), and β-gluco, (1,3,5/2,4), configurations were synthesized starting from the compounds obtained by cis-hydroxylation and oxyamination of DL-di

SYNTHESIS AND EPOXIDATION OF TRANS-5,6-DIACETOXY-1-BENZOYLOXYMETHYL-1,3-CYCLOHEXADIENE

Epoxidation of a newly prepared trans-5,6-diacetoxy-1-benzoyloxymethyl-1,3-cyclohexadiene by m-chloroperbenzoic acid in dichloroethane gave several isomeric compounds of the biologically important highly oxygenated cyclohexane derivatives.