99773-33-8

Upstream product

• 74766-78-2 3,4-di-O-acetyl-1,5-anhydro-6-bromo-2,6-dideoxy-5a-carba-DL-arabino-hex-1-enitol 

Downstream Products

• 99773-37-2 DL-1,2,3,4,7-penta-O-acetyl-(1,2/3,4)-1C-(hydroxymethyl)-1,2,3,4-cyclohexanetetrol 
• 99773-34-9 Acetic acid (3S,4R,5S)-5-acetoxy-1-oxa-spiro[2.5]oct-6-en-4-yl ester 
• 99773-34-9 DL-2,3-di-O-acetyl-1,7-anhydro-(1,2/3)-1-C-hydroxymethyl-4-cyclohexene-1,2,3-triol 
• 99773-35-0 DL-1,2,3-tri-O-acetyl-(1,2/3)-1-C-acetoxymethyl-4-cyclohexene-1,2,3-triol 

Relevant academic research and scientific papers

Pseudo-Sugars. XIV. Synthesis of Sweet-Tasting Pseudo-β-DL-fructopyranose

Pseudo-β-DL-fructopyranose was synthesized from DL-1,2-di-O-acetyl-(1,3/2)-3-5-cyclohexene-1,2-diol by a six steps reaction: Dehydrobromination, epoxidation, acetolysis, reduction, and deacetylation, in overall yield of 4.8percent.Pseudo-β-DL-fructopyrano

SYNTHESIS OF SWEET TASTING PSEUDO-β-FRUCTOPYRANOSE

Pseudo-β-DL-fructopyranose has been synthesized from DL-1,2-di-O-acetyl-(1,3/2)-3-bromomethyl-5-cyclohexene-1,2-diol by two reaction routes.The pseudosugar was found to be sweet and this fact provides a strong support for Shallenberger's sweetness-structu