74766-83-9

Upstream product

• 74766-78-2 3,4-di-O-acetyl-1,5-anhydro-6-bromo-2,6-dideoxy-5a-carba-DL-arabino-hex-1-enitol 
• 69982-70-3 3,4-di-O-acetyl-2,6-dibromo-2,6-dideoxy-5a-carba-β-DL-glucopyranosyl bromide 
• 96291-86-0 (1R)-(1,3/2)-1,2-Di-O-acetyl-3-bromomethyl-5-cyclohexene-1,2-diol 
• 96291-85-9 (1R)-(1,3,5/2,4)-3,4-diacetoxy-1,2-dibromo-5-(bromomethyl)cyclohexane 

Downstream Products

• 96291-89-3 (1S)-3,4-di-O-acetyl-1,2-anhydro-(1,2,4/3)-5-<(benzoyloxy)methyl>-5-cyclohexene-1,2,3,4-tetrol 
• 96291-88-2 (1R)-3,4-di-O-acetyl-1,2-anhydro-(1,2,3/4)-5-<(benzoyloxy)methyl>-5-cyclohexene-1,2,3,4-tetrol 
• 86747-02-6 (+)-β-senepoxide 
• 86782-19-6 (2R)-trans-2,3-diacetoxy-1-[(benzoyloxy)methyl]cyclohexa-4,6-diene 
• 96291-87-1 (1S)-(1,4/2,3)-3,4-diacetoxy-5-<(benzoyloxy)methyl>-1,2-dibromocyclohex-5-ene 
• 20421-13-0 DL-5,6-di-O-acetyl-1,2:3,4-dianhydro-(1,2,6/3,4,5)-1-C-benzoyloxymethyl-1,2,3,4,5,6-cyclohexanehexol 
• 74766-86-2 DL-3,4-di-O-Acetyl-1,2-anhydro-(1,2,3/4)-5-benzoyloxymethyl-5-cyclohexene-1,2,3,4-tetrol 
• 74766-86-2 D,L-(1,2,4/3)-3,4-di-O-acetyl-1,2-anhydro-5-benzoyloxymethyl-5-cyclohexene-1,2,3,4,-tetrol 
• 17550-38-8 DL-3,4-di-O-acetyl-1,2-anhydro-(1,2/3,4)-2C-(benzoyloxymethyl)-5-cyclohexene-1,2,3,4-tetrol 
• 74766-85-1 trans-2,3-diacetoxy-1-[(benzoyloxy)methyl]-cyclohexa-4,6-diene 
• 74766-84-0 DL-1,2-di-O-acetyl-(1,6/2,5)-3-benzoyloxymethyl-5,6-dibromo-3-cyclohexene-1,2-diol 

Relevant academic research and scientific papers

Total Synthesis of (+)-Pipoxide and (+)-β-Senepoxide and Their Diene Precursors

(2R)-trans-2,3-Diacetoxy-1-cyclohexa-4,6-diene (6), a diene precursor in the biosynthesis of highly oxygenated cyclohexane epoxides, has first been totally synthesized from the bromo lactone 16 derived from (1S)-endo-7-oxabicyclo2.2.1

SYNTHESIS AND EPOXIDATION OF TRANS-5,6-DIACETOXY-1-BENZOYLOXYMETHYL-1,3-CYCLOHEXADIENE.

The title substituted 1,3-cyclohexadiene was prepared in three steps from the readily available DL-1,2-di-O-acetyl-(1,3/2)-3-bromomethyl-5-cyclohexene-1,2-diol. Epoxidation of it with m-chloroperoxybenzoic acid in 1,2-dichloroethane afforded several stere

SYNTHESIS AND EPOXIDATION OF TRANS-5,6-DIACETOXY-1-BENZOYLOXYMETHYL-1,3-CYCLOHEXADIENE

Epoxidation of a newly prepared trans-5,6-diacetoxy-1-benzoyloxymethyl-1,3-cyclohexadiene by m-chloroperbenzoic acid in dichloroethane gave several isomeric compounds of the biologically important highly oxygenated cyclohexane derivatives.