96291-89-3

Upstream product

• 74766-85-1 trans-2,3-diacetoxy-1-[(benzoyloxy)methyl]-cyclohexa-4,6-diene 
• 96291-86-0 (1R)-(1,3/2)-1,2-Di-O-acetyl-3-bromomethyl-5-cyclohexene-1,2-diol 
• 96291-87-1 (1S)-(1,4/2,3)-3,4-diacetoxy-5-<(benzoyloxy)methyl>-1,2-dibromocyclohex-5-ene 
• 74766-83-9 Acetic acid (1S,2R,5S,6S)-2-acetoxy-5,6-dibromo-3-bromomethyl-cyclohex-3-enyl ester 
• 96291-85-9 (1R)-(1,3,5/2,4)-3,4-diacetoxy-1,2-dibromo-5-(bromomethyl)cyclohexane 
• 86782-19-6 (2R)-trans-2,3-diacetoxy-1-[(benzoyloxy)methyl]cyclohexa-4,6-diene 
• 74766-77-1 DL-di-O-acetyl-(1,3/2,4,6)-3,4-dibromo-6-benzoyloxymethyl-1,2-cyclohexanediol 
• 69982-70-3 3,4-di-O-acetyl-2,6-dibromo-2,6-dideoxy-5a-carba-β-DL-glucopyranosyl bromide 
• 74766-83-9 DL-1,2-di-O-acetyl-(1,4/2,3)-3,4-dibromo-6-bromomethyl-5-cyclohexene-1,2-diol 
• 74766-84-0 DL-1,2-di-O-acetyl-(1,6/2,5)-3-benzoyloxymethyl-5,6-dibromo-3-cyclohexene-1,2-diol 
• 74766-79-3 DL-1,2-di-O-acetyl-(1,3/2)-3-benzoyloxymethyl-5-cyclohexene-1,2-diol 
• 74766-78-2 3,4-di-O-acetyl-1,5-anhydro-6-bromo-2,6-dideoxy-5a-carba-DL-arabino-hex-1-enitol 
• 532-32-1 sodium benzoate 

Downstream Products

• 101144-24-5 methyl 4-deoxy-4-<(1R)-(1,5/4,6)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexenyl>amino-α-D-glucopyranoside 
• 101144-22-3 Methyl-4-deoxy-4-<<(1S)-(1,5/4,6)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexen-1-yl->amino>-α-D-glucopyranoside 
• 107839-11-2 Benzoic acid (3R,5S,6R)-4,5,6-triacetoxy-3-[(2R,3R,4S,5R,6S)-4,5-diacetoxy-6-((1R,2R,3S,4R,5R)-3,4-diacetoxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yloxy)-2-methyl-tetrahydro-pyran-3-ylamino]-cyclohex-1-enylmethyl ester 
• 107839-10-1 Benzoic acid (3R,5S,6R)-4,5,6-triacetoxy-3-[(2S,3R,4S,5R,6S)-4,5-diacetoxy-2-acetoxymethyl-6-((1R,2R,3S,4R,5R)-3,4-diacetoxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yloxy)-tetrahydro-pyran-3-ylamino]-cyclohex-1-enylmethyl ester 
• 141232-09-9 Benzoic acid 4,5,6-triacetoxy-3-((2S,3R,4S,5R,6S)-4,5-diacetoxy-2-acetoxymethyl-6-methoxy-tetrahydro-pyran-3-ylamino)-cyclohex-1-enylmethyl ester 
• 86964-83-2 C₅₁H₆₁NO₂₂ 
• 86964-83-2 C₅₁H₆₁NO₂₂ 
• 20421-13-0 DL-5,6-di-O-acetyl-1,2:3,4-dianhydro-(1,2,6/3,4,5)-1-C-benzoyloxymethyl-1,2,3,4,5,6-cyclohexanehexol 
• 86964-84-3 C₅₂H₆₁NO₂₄ 
• 86964-84-3 C₅₂H₆₁NO₂₄ 
• 37248-47-8 (2R,3R,4S,5S,6R)-2-[(1R,2R,3S,4S,6R)-2,3-Dihydroxy-6-hydroxymethyl-4-((1R,4S,5R,6S)-4,5,6-trihydroxy-3-hydroxymethyl-cyclohex-2-enylamino)-cyclohexyloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol 
• 87037-90-9 (2R,3R,4S,5S,6R)-2-[(1R,2R,3S,4S,6R)-2,3-Dihydroxy-6-hydroxymethyl-4-((1S,4R,5S,6R)-4,5,6-trihydroxy-3-hydroxymethyl-cyclohex-2-enylamino)-cyclohexyloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol 
• 101072-27-9 Benzoic acid (3R,4S,5R,6S)-4,5,6-triacetoxy-3-((2R,3R,4S,5R,6S)-4,5-diacetoxy-6-methoxy-2-methyl-tetrahydro-pyran-3-ylamino)-cyclohex-1-enylmethyl ester 
• 101072-27-9 Methyl 2,3-di-O-acetyl-4,6-dideoxy-4-<<(1S)-(1,4/5,6)-4,5,6-triacetoxy-3-benzoyloxymethyl-2-cyclohexen-1-yl>amino>-α-D-glucopyranoside 

Relevant academic research and scientific papers

Total Synthesis of (+)-Pipoxide and (+)-β-Senepoxide and Their Diene Precursors

(2R)-trans-2,3-Diacetoxy-1-cyclohexa-4,6-diene (6), a diene precursor in the biosynthesis of highly oxygenated cyclohexane epoxides, has first been totally synthesized from the bromo lactone 16 derived from (1S)-endo-7-oxabicyclo2.2.1

SYNTHESIS AND EPOXIDATION OF TRANS-5,6-DIACETOXY-1-BENZOYLOXYMETHYL-1,3-CYCLOHEXADIENE.

The title substituted 1,3-cyclohexadiene was prepared in three steps from the readily available DL-1,2-di-O-acetyl-(1,3/2)-3-bromomethyl-5-cyclohexene-1,2-diol. Epoxidation of it with m-chloroperoxybenzoic acid in 1,2-dichloroethane afforded several stere

SYNTHESIS AND EPOXIDATION OF TRANS-5,6-DIACETOXY-1-BENZOYLOXYMETHYL-1,3-CYCLOHEXADIENE

Epoxidation of a newly prepared trans-5,6-diacetoxy-1-benzoyloxymethyl-1,3-cyclohexadiene by m-chloroperbenzoic acid in dichloroethane gave several isomeric compounds of the biologically important highly oxygenated cyclohexane derivatives.