74785-89-0Relevant academic research and scientific papers
Metal-free synthesis of unsymmetrical organoselenides and selenoglycosides
Guan, Yong,Townsend, Steven D.
, p. 5252 - 5255 (2017/11/06)
A one-pot, metal-free procedure has been developed to synthesize unsymmetrical organoselenides. In the first step of the reaction, arylation of potassium selenocyanate (KSeCN) with an iodonium reagent proceeds in the absence of a metal catalyst to produce
Intramolecular displacement of phenylselenone by a hydroxy group: Stereoselective synthesis of 2-substituted tetrahydrofurans
Minuti, Lucio,Barattucci, Anna,Bonaccorsi, Paola Maria,Di Gioia, Maria Luisa,Leggio, Antonella,Siciliano, Carlo,Temperini, Andrea
supporting information, p. 3906 - 3909 (2013/09/02)
An efficient and stereocontrolled synthesis of 2-substituted tetrahydrofurans has been achieved. The approach employs the asymmetric reduction of γ-phenylseleno ketones obtained by three different procedures that are peculiarly applied to the synthesis of such compounds. Finally, the intramolecular substitution of the phenylselenone residue by the oxygen atom of a hydroxy group gives the tetrahydrofuran ring.
Formal α-Vinylation of Amino Acids. Use of a New Benzeneselenolate Equivalent
Pedersen, Michelle L.,Berkowitz, David B.
, p. 6965 - 6975 (2007/10/02)
A new synthetic approach to the formal α-vinylation of α-amino acids is described, in which the readily available electrophile, ethylene oxide, serves as the vinyl cation equivalent.N-Benzoyl α-amino esters bearing appropriate side-chain protecting groups
