74786-90-6Relevant academic research and scientific papers
A trans diacyloxylation of indoles
Liu, Qiang,Zhao, Qing Yong,Liu, Jie,Wu, Pan,Yi, Hong,Lei, Aiwen
supporting information; experimental part, p. 3239 - 3241 (2012/04/10)
A trans diacyloxylation of indoles is accomplished by employing PhI(OAc)2 as the oxidant. A broad range of functional groups are well tolerated. Both the electronic properties of the N-protecting groups of indoles and the acidity of the reaction media play important roles in the selectivity of indole acyloxylation reactions. The Royal Society of Chemistry 2012.
Chemo-, regio-, and stereoselective synthesis of syn -aryl glycol monoesters from aryl olefins with hydrogen peroxide catalyzed by RuCl 3
Zhang, Yanqiao,Chu, Guobiao,Cui, Xiaoxue,Han, Zhijie,Dou, Daoke,Chen, Yuanli,Yu, Xiaosong,Li, Chunbao
supporting information; experimental part, p. 1118 - 1122 (2010/06/20)
Chemo-, regio-, and stereoselectivity have been achieved in the oxidations of aryl olefins. The aryl olefins were oxidized by 2 equivalents of H 2O2 in acetic acid, catalyzed by 0.02 equivalent of RuCl3, leading to the formations of syn-aryl glycol monoesters. As the reaction is concerted, both the regio- and stereoselectivity are excellent. In the presence of aliphatic C=C bonds, the aryl C=C bonds were selectively dioxygenated. This represents the first example of chemoselective dioxygenation of aryl C=C bonds. Georg Thieme Verlag Stuttgart - New York.
REACTION OF 1-SUBSTITUTED INDOLES WITH CARBOXYLIC ACIDS AND N-IODOSUCCINIMIDE
Kwon, Sundo,Kuroki, Nobuhiko
, p. 237 - 238 (2007/10/02)
1-Substituted indoles reacted with carboxylic acids and N-iodosuccinimide to give 1-substituted-2,3-diacyloxyindolines in significant yields.
