7484-12-0

Usage

Uses

Used in Industrial Processes:
Cyclohexane, 1-chloro-2-(trichloromethyl)is utilized as a solvent in various industrial applications due to its chemical properties and stability.
Used in Pharmaceutical Synthesis:
Cyclohexane, 1-chloro-2-(trichloromethyl)serves as a starting material for the synthesis of pharmaceuticals, contributing to the development of new medications and therapeutic agents.
Used in Agrochemical Production:
Cyclohexane, 1-chloro-2-(trichloromethyl)is also employed in the production of agrochemicals, playing a role in the creation of substances that protect crops and enhance agricultural productivity.

Upstream product

• 56-23-5 tetrachloromethane 
• 110-83-8 cyclohexene 
• 94-36-0 dibenzoyl peroxide 

Downstream Products

• 51317-56-7 1-Dichlormethyl-2-chlor-cyclohexan 

Relevant academic research and scientific papers

Kharasch addition of tetrachloromethane to alkenes catalyzed by metal acetylacetonates

Various transition metal acetylacetonates have proven to be efficient catalytic systems for the Kharasch addition of tetrachloromethane to alkenes under mild conditions, providing 1:1 adducts in up to 87% yield, based on internal standard. The nature of metal, solvent, temperature, olefin/CCl 4 ratio and the presence of nucleophilic co-catalysts were tested to evaluate the scope and limitation of the reaction.

Addition of CCl4 to olefins catalyzed by chromium and ruthenium complexes: The influence of water as a nucleophilic additive

The feasibility of the addition of CCl4 to linear and cyclic olefins and dienes in the presence of chromium and ruthenium complexes was established. The influence of water as a nucleophilic additive and the influence of the olefin nature, the c

Metal phthalocyanine-catalyzed addition of polychlorine-containing organic compounds to C=C bonds

Organopolychlorine compounds (CCl4, CCl3CO 2Et, CCl3CHO) add at the double bond of various olefins under the catalysis of the metal phthalocyanine complexes. A possibility of quantitative catalyst recovery was shown.

Exploring the substrate scope of the Ru(II)-catalyzed kharasch reaction

The Kharasch reaction, or atom-transfer addition of polyhalogenated alkanes to alkenes is known to be catalyzed by a number of Ru(II) complexes. The easily prepared [RuCl2(PPh3)3] was used to investigate the reaction scope. A number of halogenated alkanes were added to a range of alkenes with good to excellent regioselectivities.

Reactivity of γ-chloro-gem-trichloroalkanes with chromous chloride

CrCl2-mediated condensation of γ-chloro-gem-trichloroalkanes with aldehyde generates homoallylic alcohols through a hydride rearrangement followed by a Nozaki-Hiyama allylation.

Addition of tetrachloromethane to alkenes, catalyzed by Pt(II) complexes

Platinum(II) complexes [dichlorobis(triphenylphosphine)platinum(II), dichlorobis(tri-m-tolylphosphine)platinum(II), dichloro(2,9-dimethyl-1,10-N, N′-phenanthroline)platinum(II), etc.] showed catalytic activity in addition of tetrachloromethane across the double bond in 1-hexene, 1-heptene, 1-octene, 1-decene, and cyclohexene. The stability of the platinum catalysts was evaluated by GLC, gas chromatography-mass spectrometry, and 31P NMR and IR spectroscopy; the kinetic relationships of the addition reactions were determined. A reaction mechanism involving formation of trichloromethyl radical was suggested. A correlation was revealed for the first time between the catalytic activity of platinum, palladium, and rhodium complexes and the capability of these complexes to generate hexachloroethane. 2005 Pleiades Publishing, Inc.

Addition of carbon tetrachloride to unsaturated compounds catalyzed by manganese, vanadium, and molybdenum complexes

It was found that CCl4 can add to linear and cyclic olefins and dienes in the presence of manganese, vanadium, and molybdenum complexes. The effects of the olefin nature, temperature, reaction time, the nature of the catalyst central atom, and

Addition of α-polyhalides to olefins under mild reaction conditions, catalyzed by Mo(CO)6

Mo(CO)6 was found to be an efficient pre-catalyst in the 1,2-addition reaction of α-polyhalides to various olefins. Significantly, the reaction was run under mild conditions, viz. refluxing acetonitrile, with satisfactory yields. Cr(CO)6/

The Fe0 promoted addition of CCl4 and CCl3Br to olefins

The radical addition of CCl4 or CCl3Br to olefins is efficiently promoted by iron filings in N,N-dimethylformamide under mild conditions.

ADDITION OF POLYHALOGENO DERIVATIVES TO OLEFINS IN THE PRESENCE OF DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II) AND PROPYLAMAGNESIUM BROMIDE

Bromotrichloromethane and carbon tetrachloride add to monosubstituted and 2,2- and 1,2-disubstituted and trisubstituted olefins in the presence of the products from the reaction of nickel(II) complexes and alkylmagnesium halides.The trichloromethyl group is attached to the least substituted carbon atom of the double bond.