74878-72-1

Basic information

• Product Name: N,N-DIBUTYL-M-TOLUIDINE
• Synonyms: N,N-DIBUTYL-M-TOLUIDINE;N,N-dibutyl-3-methylbenzenamine
• CAS NO: 74878-72-1
• Molecular Formula: C₁₅H₂₅N
• Molecular Weight: 219.37
• Mol File: 74878-72-1.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N,N-DIBUTYL-M-TOLUIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-DIBUTYL-M-TOLUIDINE(74878-72-1)
• EPA Substance Registry System: N,N-DIBUTYL-M-TOLUIDINE(74878-72-1)

Safety Data

• Hazardous Substances Data: 74878-72-1(Hazardous Substances Data)

Upstream product

• 109-65-9 1-bromo-butane 
• 108-44-1 1-amino-3-methylbenzene 
• 638-03-9 m-toluidine hydrochloride 
• 71-36-3 butan-1-ol 
• 1643-19-2 tetrabutylammomium bromide 
• 109-74-0 propyl cyanide 
• 99-08-1 1-methyl-3-nitrobenzene 
• 108-41-8 1-chloro-3-methylbenzene 
• 111-92-2 dibutylamine 
• 95-46-5 2-methylphenyl bromide 
• 95-49-8 2-methylchlorobenzene 
• 542-69-8 1-iodo-butane 

Downstream Products

• 105810-37-5 Bis<2-methyl-4-(dibutylamino)phenyl>squaraine 

Relevant articles and documents

Factors Affecting Virus Photoinactivation by a Series of Phenothiazine Dyes

A series of four phenothiazine dyes, including methylene blue (MB), were previously tested for their ability to photoinactivate viruses in red cell suspensions. One of the dyes, 1,9-dimethyl-3-dimethylamino-7-dimethylaminophenothiazine (1,9-dimethylmethyl

Reductive monoalkylation of aromatic and aliphatic nitro compounds and the corresponding amines with nitriles

(Chemical Equation Presented) A simple, selective, rapid, and efficient procedure for the synthesis of secondary amines from the reductive alkylation of either aliphatic or aromatic nitro compounds and the corresponding amines is reported. Ammonium formate is used as the hydrogen source and Pd/C as the hydrogen transfer catalyst. The reaction is carried out at room temperature. The rate differences for the preferential formation of secondary over tertiary products are due to both steric and electronic factors.

Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C-C, C-N, and C-O bond-forming cross-couplings

Pentaphenylferrocenyl di-tert-butylphosphine has been prepared in high yield from a two-step synthetic procedure, and the scope of various cross-coupling processes catalyzed by complexes bearing this ligand has been investigated. This ligand creates a remarkably general palladium catalyst for aryl halide amination and for Suzuki coupling. Turnovers of roughly 1000 were observed for aminations with unactivated aryl bromides or chlorides. In addition, complexes of this ligand catalyzed the formation of selected aryl ethers under mild conditions. The reactions encompassed electron-rich and electron-poor aryl bromides and chlorides. In the presence of catalysts containing this ligand, these aryl halides coupled with acyclic or cyclic secondary alkyl- and arylamines, with primary alkyl- and arylamines, and with aryl- and primary alkylboronic acids. These last couplings provide the first general procedure for reaction of terminal alkylboronic acids with aryl halides without toxic or expensive bases. The ligand not only generates highly active palladium catalysts, but it is air stable in solution and in the solid state. Palladium(0) complexes of this ligand are also air stable as a solid and react only slowly with oxygen in solution.