749254-91-9

Basic information

• Product Name: 2H-Pyrrole,3,4-dihydro-4-[(4-methoxyphenyl)methylene]-,(4E)-(9CI)
• Synonyms: 2H-Pyrrole,3,4-dihydro-4-[(4-methoxyphenyl)methylene]-,(4E)-(9CI)
• CAS NO: 749254-91-9
• Molecular Formula: C₁₂H₁₃NO
• Molecular Weight: 0
• Product Categories: METHOXY
• Mol File: 749254-91-9.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2H-Pyrrole,3,4-dihydro-4-[(4-methoxyphenyl)methylene]-,(4E)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Pyrrole,3,4-dihydro-4-[(4-methoxyphenyl)methylene]-,(4E)-(9CI)(749254-91-9)
• EPA Substance Registry System: 2H-Pyrrole,3,4-dihydro-4-[(4-methoxyphenyl)methylene]-,(4E)-(9CI)(749254-91-9)

Safety Data

• Hazardous Substances Data: 749254-91-9(Hazardous Substances Data)

Upstream product

• 123-75-1 pyrrolidine 
• 123-11-5 4-methoxy-benzaldehyde 
• 5981-17-9 dodecahydro-3a,6a,9a-triaza-trindene 

Downstream Products

• 749254-93-1 (Z)-4-(4-methyoxybenzylidene)-3,4-dihydro-2H-pyrrole 

Relevant articles and documents

Direct β-C(sp3)-H Functionalization of Aliphatic Amines to α,β-Unsaturated Imines, Aldehydes, and Chromenes

A metal-free method for direct β-C(sp3)-H functionalization of aliphatic amine was developed. The method is based on a reaction that yields enamine directly from the corresponding aliphatic amine, which otherwise requires the aid of metallic reagent and/or external oxidant. The reaction is operationally simple, general, and highly efficient in functionalizing both cyclic and acyclic amines. Structurally diverse unsaturated imines were obtained from N-heterocycles, while acyclic amines provided 2-alkyl cinnamaldehyde and benzopyran derivatives with excellent E/Z-selectivity.