749254-91-9Relevant academic research and scientific papers
Direct β-C(sp3)-H Functionalization of Aliphatic Amines to α,β-Unsaturated Imines, Aldehydes, and Chromenes
Mandal, Sumana,Mahato, Sujit,Jana, Chandan K.
supporting information, p. 3762 - 3765 (2015/08/18)
A metal-free method for direct β-C(sp3)-H functionalization of aliphatic amine was developed. The method is based on a reaction that yields enamine directly from the corresponding aliphatic amine, which otherwise requires the aid of metallic reagent and/or external oxidant. The reaction is operationally simple, general, and highly efficient in functionalizing both cyclic and acyclic amines. Structurally diverse unsaturated imines were obtained from N-heterocycles, while acyclic amines provided 2-alkyl cinnamaldehyde and benzopyran derivatives with excellent E/Z-selectivity.
Design and photochemical characterization of a biomimetic light-driven Z/E switcher
Sampedro, Diego,Migani, Annapaola,Pepi, Alessandra,Busi, Elena,Basosi, Riccardo,Latterini, Loredana,Elisei, Fausto,Fusi, Stefania,Ponticelli, Fabio,Zanirato, Vinicio,Olivucci, Massimo
, p. 9349 - 9359 (2007/10/03)
Protonated Schiff bases (PSBs) of polyenals constitute a class of light-driven switchers selected by biological evolution that provide model compounds for the development of artificial light-driven molecular devices or motors. In the present paper, our pr
