749256-67-5

Upstream product

• 108-24-7 acetic anhydride 
• 520-29-6 5,4'-dihydroxy-7-methoxyflavanone 
• 1195628-34-2 sakuranin 
• 73111-01-0 4',5,7-triacetoxyflavan-4-one 
• 80-11-5 N-methyl-N-nitrosotoluene-p-sulfonamide 
• 74-88-4 methyl iodide 
• 480-41-1 5,7-Dihydroxy-2-(4-hydroxy-phenyl)-chroman-4-on 
• 123-08-0 4-hydroxy-benzaldehyde 
• 75-36-5 acetyl chloride 

Downstream Products

• 749256-70-0 4'-acetoxy-8-C-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-5-hydroxy-7-methoxyflavan 
• 520-29-6 5,4'-dihydroxy-7-methoxyflavanone 
• 88607-74-3 4'-acetoxy-5-hydroxy-7-methoxynaringenin 
• 25163-67-1 2',4,4',6'-tetramethoxychalcone 

Relevant academic research and scientific papers

Simple synthesis of sakuranetin and selinone via a common intermediate, utilizing complementary regioselectivity in the deacetylation of naringenin triacetate

Sakuranetin and selinone were successfully synthesized utilizing the regioselective deacetylation of naringenin triacetate. Deacetylation of the latter at C-7 with imidazole in 1,4-dioxane at 40°C furnished the corresponding diacetate in 80% yield. Methyl

Total synthesis of flavocommelin, a component of the blue supramolecular pigment from Commelina communis, on the basis of direct 6-C-glycosylation of flavan

We succeeded in a first total synthesis of flavocommelin (1), a component of the blue supramolecular pigment, commelinin (2), from Commelina communis, by direct 6-C-glycosylation of the flavan 4 using perbenzylglucosyl fluoride 8 in the presence of MS 5 A in CH2Cl2 and a catalytic amount of BF3·Et2O. After 6-C-glycosylation of 4, oxidation with CAN to flavanone 18 and subsequent 4′-O-glycosylation, promoted with a combination of BF3·Et2O and DTBMP, afforded diglucosylflavanone 20. DDQ oxidation of 20 and deprotection successively gave 1.