7493-02-9

Basic information

• Product Name: (3aS,7aS)-Octahydro-benzo[c]thiophene
• CAS NO: 7493-02-9
• Molecular Weight: 142.265
• Mol File: 7493-02-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (3aS,7aS)-Octahydro-benzo[c]thiophene(CAS DataBase Reference)
• NIST Chemistry Reference: (3aS,7aS)-Octahydro-benzo[c]thiophene(7493-02-9)
• EPA Substance Registry System: (3aS,7aS)-Octahydro-benzo[c]thiophene(7493-02-9)

Safety Data

• Hazardous Substances Data: 7493-02-9(Hazardous Substances Data)

Upstream product

• 3710-30-3 1,7-Octadiene 
• 4841-85-4 trans-1,2-bis(ethoxycarbonyl)-4-cyclohexene 
• 96836-97-4 diethyl cyclohexane-trans-1,2-dicarboxylate 
• 76155-27-6 (+/-)-trans-2-(hydroxymethyl)cyclohexylmethanol 
• 3205-36-5 trans-1,2-bis(hydroxymethyl)cyclohexane di-p-toluene-sulfonate 
• 13019-30-2 trans-1,2-bis(bromomethyl)cyclohexane 

Relevant articles and documents

Metallacycle transfer from zirconium to main group elements: A versatile synthesis of heterocycles

The reaction of zirconium metallacycles is used to produce a variety of main group heterocycles including borole Diels-Alder dimers, galloles, indacyclopentadienes, siloles, germoles, stannoles, phospholes, arsoles, stiboles, bismoles, thiophenes, selenophenes, dihydrothiophenes, dihydroselenophenes, tetrahydrothiophenes, tetrahydro-selenophenes, stannacyclopentanes, phospholenes, and isothiazoles. An X-ray crytallographic study of the borole DielsAlder dimer of 1-phenyl-2,3,4,5-tetramethylborole is discussed and compared with the structure of 7-norbornenyl carbenium ions. The scope and potential for this metallacycle transfer reaction are delineated.

Zirconium-Mediated Ring Construction from Dienes: Remarkable Effect of Ligands on Stereochemistry

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