749924-31-0

Upstream product

• 749924-30-9 (5Z,8S,9R)-8-(tert-butyldiphenylsilanyloxy)-9-(tert-butyldiphenylsilanyloxymethyl)-2-(phenylselenylmethyl)-2,3,4,7,8,9-hexahydrooxonine 
• 749924-29-6 (8S,9R)-8-(tert-butyldiphenylsilanyloxy)-9-(tert-butyldiphenylsilanyloxymethyl)-2-methylene-2,3,4,7,8,9-hexahydrooxonine 
• 148903-89-3 (Z)-(8S,9R)-8-tert-butyldiphenylsilyloxy-9-tert-butyldiphenylsilyloxymethyl-2,3,4,7,8,9-hexahydro-oxonin-2-one 

Downstream Products

• 749924-32-1 (E)-3-[(Z)-(2R,8S,9R)-8-(tert-Butyl-diphenyl-silanyloxy)-9-(tert-butyl-diphenyl-silanyloxymethyl)-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-2-methyl-propenal 
• 749924-35-4 (Z)-(2S,3S,9R)-3-(tert-Butyl-diphenyl-silanyloxy)-9-((E)-2-methyl-buta-1,3-dienyl)-2,3,4,7,8,9-hexahydro-oxonine-2-carbaldehyde 
• 749924-34-3 [(Z)-(2R,3S,9R)-3-(tert-Butyl-diphenyl-silanyloxy)-9-((E)-2-methyl-buta-1,3-dienyl)-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-methanol 
• 749924-33-2 (Z)-(2R,3S,9R)-3-(tert-Butyl-diphenyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-9-((E)-2-methyl-buta-1,3-dienyl)-2,3,4,7,8,9-hexahydro-oxonine 
• 852213-31-1 (1S,3S,4R,6R,9S)-3-(tert-butyldiphenylsilanyloxy)-4-hydroxymethyl-6-vinyl-5,10-dioxabicyclo[7.1.0]decane 
• 852213-27-5 (1S,3S,4R,6R,9R)-3-(tert-butyldiphenylsilanyloxy)-4,6-divinyl-5,10-dioxabicyclo[7.1.0]decane 
• 852213-26-4 (1S,3S,4R,6R,9R)-3-(tert-butyldiphenylsilanyloxy)-6-vinyl-5,10-dioxabicyclo[7.1.0]decane-4-carbaldehyde 
• 852213-25-3 (2R,5Z,8S,9R)-8-(tert-butyldiphenylsilanyloxy)-9-hydroxymethyl-2-vinyl-2,3,4,7,8,9-hexahydrooxonine 
• 852213-20-8 (2R,5Z,8S,9R)-8-(tert-butyldiphenylsilanyloxy)-2,9-divinyl-2,3,4,7,8,9-hexahydrooxonine 
• 852213-30-0 (2R,5Z,8S,9R)-8-(tert-butyldiphenylsilanyloxy)-2-vinyl-2,3,4,7,8,9-hexahydrooxonine-9-carbaldehyde 
• 852213-28-6 (1R,2S,4S,6R,9R,10Z)-2-(tert-butyldiphenylsilanyloxy)-5,12-dioxatricyclo[7.2.1.0(4,6)]-dodec-10-ene 
• 852213-21-9 (1S,2S,4Z,8R,9Z)-2-(tert-butyldiphenylsilanyloxy)-11-oxabicyclo[6.2.1]undeca-4,9-diene 
• 852213-23-1 (2R,5Z,8S,9R)-8-(tert-butyldiphenylsilanyloxy)-9-(tert-butyldiphenylsilanyloxymethyl)-2-vinyl-2,3,4,7,8,9-hexahydrooxonine 

Relevant academic research and scientific papers

Synthesis of simplified analogues of eleutherobin via a Claisen rearrangement/RCM strategy

The enantioselective synthesis of a number of simplified analogues of the cytotoxic natural product eleutherobin is reported.

The synthesis and biological evaluation of novel eunicellin analogues

The intramolecular Diels-Alder reaction of a 2,9-disubstituted hexahydro-Δ5.6-oxonin derivative 14 afforded two diastereomeric tricyclic eunicellin analogues 15 and 16, which were desilylated to produce the alcohols 17 and 3; these were found t