75010-96-7Relevant academic research and scientific papers
Synthesis of 1,3-Cycloalkadienes from Cycloalkenes: Unprecedented Reactivity of Oxoammonium Salts
Nagasawa, Shota,Sasano, Yusuke,Iwabuchi, Yoshiharu
, p. 13189 - 13194 (2016/10/30)
Few methods allow for the direct conversion of cycloalkenes into cycloalkadienes with high chemo- and regioselectivity. Herein, we report a convenient one-pot process for this transformation that involves the unprecedented N-preferential group transfer of N-oxoammonium salts to cycloalkenes, followed by Cope elimination, to afford cycloalkadienes at room temperature and pressure.
Type A Zwitterions and Cyclohexadienone Photochemical Rearrangements. Mechanistic and Exploratory Organic Photochemistry
Zimmerman, Howard E.,Pasteris, Robert J.
, p. 4876 - 4891 (2007/10/02)
The photochemistry of 3-methoxy-4,4-diphenyl-2,5-cyclohexadienone was studied.The type A rearrangement proved to be regioselective with a preference for formation of 4-methoxy-6,6-diphenylbicyclohex-3-en-2-one relative to 5-methoxy-6,6-diphenylbicy
