75057-01-1

Basic information

• Product Name: Benzene, 1,1'-ethenylidenebis[4-(methylthio)-
• CAS NO: 75057-01-1
• Molecular Formula: C16H16S2
• Molecular Weight: 272.435
• Mol File: 75057-01-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-ethenylidenebis[4-(methylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-ethenylidenebis[4-(methylthio)-(75057-01-1)
• EPA Substance Registry System: Benzene, 1,1'-ethenylidenebis[4-(methylthio)-(75057-01-1)

Safety Data

• Hazardous Substances Data: 75057-01-1(Hazardous Substances Data)

Upstream product

• 100-68-5 methyl-phenyl-thioether 
• 75-36-5 acetyl chloride 
• 460742-71-6 1,1-bis(p-methylthiophenyl)ethyl p-nitrobenzoate 
• 141-78-6 ethyl acetate 
• 93017-98-2 2-Brom-1,1-bis-(4-methylmercapto-phenyl)-ethan 
• 460742-46-5 1,1-Bis-(4-methylsulfanyl-phenyl)-ethanol 

Downstream Products

• 75057-05-5 C₃₂H₃₀S₄ 
• 100835-62-9 1,1-bis-(p-methylsulphonylphenyl)ethene 
• 100835-66-3 2,2-bis-(p-methylthiophenyl)ethyl tosylate 
• 75057-02-2 C₃₂H₃₀O₂S₂ 
• 75057-13-5 2,2-bis(p-methylthiophenyl)acetaldehyde 
• 75057-11-3 trans-1,2-di-p-methylthiophenylethylene 
• 100848-93-9 2,2-bis-(p-methylthiophenyl)ethyl chloride 

Relevant articles and documents

Convenient and efficient synthesis of 1,1-bis-(4-alkylthiophenyl)-1-alkenes via tandem Friedel-Crafts acylation and alkylation of sulfides and acyl chlorides

1,1-Bis(4-alkylthiophenyl)-1-alkenes were conveniently and efficiently prepared from alkyl phenyl sulfides and acyl chlorides via a tandem Friedel-Crafts acylation and alkylation in the presence of anhydrous aluminum chloride. The scope, limitation, and mechanism of the tandem reaction were also discussed. Copyright Taylor & Francis, Inc.

Substituent Effect Studies of Aryl-Assisted Solvolyses. I. The Acetolysis of 2,2-Bis(substituted phenyl)ethyl p-Toluenesulfonates

The substituent effect on the acetolysis of 2,2-bis(substituted phenyl)ethyl p-toluenesulfonates at 90.10 deg C can be described accurately in terms of the Yukawa-Tsuno (LArSR) relationship, giving a ρ value of -4.44 and an r value of 0.53. The substituent effect correlation of this system carrying two aryls is quite comparable to that of the 2-methyl-2-phenylpropyl system carrying a single aryl group, suggesting the close similarity in the structure of the transition states between the systems. The results can be reasonably accounted for on the basis of the accepted mechanism of this reaction, involving a rate-determining aryl-assisted transition state where only one aryl group of the two β-aryl groups participates.