750594-47-9

Basic information

• Product Name: (1R,2S,5R)-1-[(E)-3-(tert-Butyl-diphenyl-silanyloxy)-propenyl]-2-isopropyl-5-methyl-cyclohexanol
• Synonyms: (1R,2S,5R)-1-[(E)-3-(tert-Butyl-diphenyl-silanyloxy)-propenyl]-2-isopropyl-5-methyl-cyclohexanol
• CAS NO: 750594-47-9
• Molecular Weight: 450.737
• Mol File: 750594-47-9.mol

Chemical Properties

• CAS DataBase Reference: (1R,2S,5R)-1-[(E)-3-(tert-Butyl-diphenyl-silanyloxy)-propenyl]-2-isopropyl-5-methyl-cyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,5R)-1-[(E)-3-(tert-Butyl-diphenyl-silanyloxy)-propenyl]-2-isopropyl-5-methyl-cyclohexanol(750594-47-9)
• EPA Substance Registry System: (1R,2S,5R)-1-[(E)-3-(tert-Butyl-diphenyl-silanyloxy)-propenyl]-2-isopropyl-5-methyl-cyclohexanol(750594-47-9)

Safety Data

• Hazardous Substances Data: 750594-47-9(Hazardous Substances Data)

Upstream product

• 88159-06-2 tert-butyl(diphenyl)(2-propynyloxy)silane 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 10458-14-7 (2R,5S)-menthone 
• 750594-46-8 (E)-1-(tert-butyldiphenylsilyloxy)-3-iodoprop-2-ene 

Downstream Products

• 750594-53-7 tert-Butyl-{(S)-3-[(2S,5R)-2-isopropyl-5-methyl-cyclohex-(E)-ylidene]-2-naphthalen-1-yl-propoxy}-diphenyl-silane 
• 750594-54-8 tert-Butyl-{(S)-3-[(2S,5R)-2-isopropyl-5-methyl-cyclohex-(E)-ylidene]-2-naphthalen-2-yl-propoxy}-diphenyl-silane 
• 750594-76-4 [2-(tert-butyl-diphenyl-silanyloxy)-1-naphthalen-1-yl-ethyl]-carbamic acid methyl ester 
• 750594-75-3 3-(tert-butyl-diphenyl-silanyloxy)-2-naphthalen-1-yl-propionic acid 
• 750594-63-9 {(S)-2-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-1-naphthalen-1-yl-ethyl}-carbamic acid methyl ester 
• 750594-62-8 (S)-3-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-2-naphthalen-1-yl-propionic acid 
• 750594-66-2 {(S)-2-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-1-naphthalen-2-yl-ethyl}-carbamic acid methyl ester 
• 750594-65-1 (S)-3-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-2-naphthalen-2-yl-propionic acid 
• 750594-61-7 (S)-3-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-2-naphthalen-1-yl-propan-1-ol 
• 750594-64-0 (S)-3-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-2-naphthalen-2-yl-propan-1-ol 
• 750594-49-1 Carbonic acid (1R,2S,5R)-1-[(E)-3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-2-isopropyl-5-methyl-cyclohexyl ester methyl ester 

Relevant articles and documents

A stereodivergent approach to amino acids, amino alcohols, or oxazolidinones of high enantiomeric purity

(-)-Menthone, an inexpensive chiral auxiliary, was used to prepare both enantiomers of α-amino acids, amino alcohols, or oxazolidinones. The sequence includes the SN2′ displacement by a cuprate reagent and a Curtius rearrangement as key steps.