750594-63-9

Basic information

• Product Name: {(S)-2-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-1-naphthalen-1-yl-ethyl}-carbamic acid methyl ester
• Synonyms: {(S)-2-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-1-naphthalen-1-yl-ethyl}-carbamic acid methyl ester
• CAS NO: 750594-63-9
• Molecular Weight: 365.516
• Mol File: 750594-63-9.mol

Chemical Properties

• CAS DataBase Reference: {(S)-2-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-1-naphthalen-1-yl-ethyl}-carbamic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: {(S)-2-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-1-naphthalen-1-yl-ethyl}-carbamic acid methyl ester(750594-63-9)
• EPA Substance Registry System: {(S)-2-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-1-naphthalen-1-yl-ethyl}-carbamic acid methyl ester(750594-63-9)

Safety Data

• Hazardous Substances Data: 750594-63-9(Hazardous Substances Data)

Upstream product

• 750594-53-7 tert-Butyl-{(S)-3-[(2S,5R)-2-isopropyl-5-methyl-cyclohex-(E)-ylidene]-2-naphthalen-1-yl-propoxy}-diphenyl-silane 
• 750594-49-1 Carbonic acid (1R,2S,5R)-1-[(E)-3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-2-isopropyl-5-methyl-cyclohexyl ester methyl ester 
• 750594-47-9 (1R,2S,5R)-1-[(E)-3-(tert-Butyl-diphenyl-silanyloxy)-propenyl]-2-isopropyl-5-methyl-cyclohexanol 
• 750594-61-7 (S)-3-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-2-naphthalen-1-yl-propan-1-ol 
• 124-41-4 sodium methylate 
• 750594-62-8 (S)-3-[(2S,5R)-2-Isopropyl-5-methyl-cyclohex-(E)-ylidene]-2-naphthalen-1-yl-propionic acid 

Relevant articles and documents

A stereodivergent approach to amino acids, amino alcohols, or oxazolidinones of high enantiomeric purity

(-)-Menthone, an inexpensive chiral auxiliary, was used to prepare both enantiomers of α-amino acids, amino alcohols, or oxazolidinones. The sequence includes the SN2′ displacement by a cuprate reagent and a Curtius rearrangement as key steps.