75067-08-2

Upstream product

• 27126-76-7 [hydroxy(tosyloxy)iodo]benzene 
• 149-73-5 trimethyl orthoformate 
• 591-50-4 iodobenzene 
• 104-15-4 toluene-4-sulfonic acid 

Downstream Products

• 106251-11-0 N-phenyliodonio acetamide tosylate 
• 591-50-4 iodobenzene 
• 120188-75-2 methoxydimethylsulfonium tosylate 
• 120188-80-9 C₇H₁₇OS⁽¹⁺⁾*C₇H₇O₃S^(1-) 
• 106251-14-3 C₁₀H₁₃INO⁽¹⁺⁾*C₇H₇O₃S^(1-) 
• 106251-16-5 C₁₂H₁₇INO⁽¹⁺⁾*C₇H₇O₃S^(1-) 
• 106251-15-4 C₁₁H₁₅INO⁽¹⁺⁾*C₇H₇O₃S^(1-) 
• 120188-78-5 C₈H₁₀BrOS⁽¹⁺⁾*C₇H₇O₃S^(1-) 
• 120188-76-3 C₁₅H₁₇OS⁽¹⁺⁾*C₇H₇O₃S^(1-) 
• 106266-43-7 N-phenyliodonio α-phenylacetamide tosylate 
• 5433-22-7 cis-1,2-bis(tosyloxy)cyclohexane 
• 1016-09-7 benzhydryl methyl ether 
• 77525-91-8 1-methoxy-4-(1-methoxy-ethyl)-benzene 
• 1678-43-9 1-benzoyl-1-phenylmethyl p-toluenesulfonate 

Relevant academic research and scientific papers

Synthesis of Sulfoximidoyl-Containing Hypervalent Iodine(III) Reagents and Their Use in Transition-Metal-Free Sulfoximidations of Alkynes

Well-defined hypervalent iodine(III) reagents incorporating transferable sulfoximidoyl groups were obtained through ligand exchange reactions of methoxy(tosyloxy)iodobenzene (MTIB) with NH sulfoximines in good to excellent yields. The solid-state structure of a representative product was characterized by X-ray crystallography. Utilizing these reagents in synthesis provides a new, transition-metal-free approach towards N-alkynylated sulfoximines.