benzene

Base Information

• Chemical Name: benzene
• CAS No.: 75067-08-2
• Molecular Formula: C₁₄H₁₅IO₄S
• Molecular Weight: 406.241
• Mol file: 75067-08-2.mol

Synonyms:benzene

Chemical Property of benzene

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzene

There total 2 articles about benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

[hydroxy(tosyloxy)iodo]benzene (27126-76-7) + trimethyl orthoformate (149-73-5) → benzene (75067-08-2)

Guidance literature:

for 8h; Ambient temperature;

DOI:10.1021/jo01312a036

Reference yield:

iodobenzene (591-50-4) + toluene-4-sulfonic acid (104-15-4) + trimethyl orthoformate (149-73-5) → benzene (75067-08-2)

Guidance literature:

iodobenzene; toluene-4-sulfonic acid; With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 2h;

trimethyl orthoformate; for 12h;

DOI:10.1002/anie.201605743

Reference yield: 100.0%

(-)-menthol (2216-51-5) + benzene (75067-08-2) → <<(-)-menthyloxy>(tosyloxy)iodo>benzene (128328-14-3,128328-15-4)

Guidance literature:

In dichloromethane;

DOI:10.1021/ja00170a059

upstream raw materials:

[hydroxy(tosyloxy)iodo]benzene

trimethyl orthoformate

iodobenzene

toluene-4-sulfonic acid

Downstream raw materials:

N-phenyliodonio acetamide tosylate

iodobenzene

methoxydimethylsulfonium tosylate

C₇H₁₇OS⁽¹⁺⁾*C₇H₇O₃S^(1-)