75148-49-1

Basic information

• Product Name: 3-BROMOBENZALDEHYDE DIETHYL ACETAL
• Synonyms: 1-BROMO-3-DIETHOXYMETHYL-BENZENE;3-BROMOBENZALDEHYDE DIETHYL ACETAL;3-Bromo-alpha,alpha-diethoxytoluene;BENZENE,1-BROMO-3-(DIETHOXYMETHYL);3-Bromobenzaldehyde diethyl acetal,95%;3-BroMobenzaldehyde diethyl acetal, 95% 10ML;3-BroMobenzaldehyde diethyl acetal, 95% 50ML
• CAS NO: 75148-49-1
• Molecular Formula: C₁₁H₁₅BrO₂
• Molecular Weight: 259.14
• EINECS: -0
• Product Categories: Adehydes, Acetals & Ketones;Bromine Compounds;Acetals/Ketals/Ortho Esters;Organic Building Blocks;Oxygen Compounds
• Mol File: 75148-49-1.mol
• Article Data: 9

Chemical Properties

• Melting Point: 95°C/1mm
• Boiling Point: 95 °C0.5 mm Hg(lit.)
• Flash Point: 219 °F
• Appearance: clear colorless liquid
• Density: 1.271 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0125mmHg at 25°C
• Refractive Index: n20/D 1.512(lit.)
• Storage Temp.: 2-8°C
• BRN: 6392356
• CAS DataBase Reference: 3-BROMOBENZALDEHYDE DIETHYL ACETAL(CAS DataBase Reference)
• NIST Chemistry Reference: 3-BROMOBENZALDEHYDE DIETHYL ACETAL(75148-49-1)
• EPA Substance Registry System: 3-BROMOBENZALDEHYDE DIETHYL ACETAL(75148-49-1)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36-37/39
• WGK Germany: 3
• Hazardous Substances Data: 75148-49-1(Hazardous Substances Data)

Usage

Chemical Properties

clear colorless liquid

Uses

3-Bromobenzaldehyde diethyl acetal may be used in the preparation of 3-(tris[2-perfluorohexylethyl]stannyl)benzaldehyde.

General Description

3-Bromobenzaldehyde diethyl acetal is an acetal derivative of 3-bromobenzaldehyde.

InChI:InChI=1/C11H15BrO2/c1-3-13-11(14-4-2)9-6-5-7-10(12)8-9/h5-8,11H,3-4H2,1-2H3

Upstream product

• 3132-99-8 m-bromobenzoic aldehyde 
• 64-17-5 ethanol 
• 122-51-0 orthoformic acid triethyl ester 
• 998-30-1 Triethoxysilane 

Downstream Products

• 160515-73-1 Si,Si,1,1'-tetramethyl-5,5'-silanediyl-bis-benzaldehyde diethylacetal 
• 179942-61-1 ethyl 1-cyclopropyl-7-(3-diethoxymethyl-phenyl)-6-fluoro-1,4-dihydro-4-oxo-quinoline-3-carboxylate 
• 1239713-23-5 C₂₁H₁₅NO₃ 
• 1567979-48-9 3-dimesitylborylbenzaldehyde 
• 1567979-58-1 Mes₂B(C₆H₄)CH(C₄H₄N)2 
• 14394-73-1 (E)-ethyl 3-(3-bromophenyl)-2-cyanoacrylate 
• 2972-74-9 2-(3-bromobenzylidene)malononitrile 
• 103668-99-1 1-(3-thiophen-2'yl)-phenylcarboxaldehyde 
• 1256169-81-9 2-(3-(diethoxymethyl)phenyl)thiophene 
• 405151-76-0 C₁₆H₁₅BrN₂O₃ 
• 298230-74-7 C₁₄H₁₁BrN₂O 

Relevant articles and documents

Practical acetalization and transacetalization of carbonyl compounds catalyzed by recyclable PVP-I

A novel PVP-I catalyzed acetalizations/transacetalizations of carbonyl compounds has been developed processing with a mild and easy handling fashion. Different types of Acyclic and cyclic acetals were prepared from carbonyl compounds or their acetals successfully. Further applications of newly developed catalytic combination were testified. This protocol featured with simplicity of operation, mild reaction condition, short reaction time, recyclable of catalyst and broad substrates scope with excellent yields.

Triarylborane-dipyrromethane conjugates bearing dual receptor sites: The synthesis and evaluation of the anion binding site preference

The synthesis and optical properties of four new triarylborane- dipyrromethane (TAB-DPM) conjugates (3a-d) containing dual binding sites (hydrogen bond donor and Lewis acid) have been reported. The new compounds exhibit a selective fluorogenic response towards the F- ion. The NMR titrations show that the anions bind to the TAB-DPM conjugates via the Lewis acidic triarylborane centre in preference to the hydrogen bond donor (dipyrromethane) units.

Iron(III) tosylate in the preparation of dimethyl and diethyl acetals from ketones and β-keto enol ethers from cyclic β-diketones

An efficient method for conversion of ketones to their corresponding dimethyl and diethyl acetals and of cyclic β-diketones into β-keto enol ethers using Fe(OTs)3 as a catalyst is described. Copyright Taylor & Francis Group, LLC.