75213-31-9

Basic information

• Product Name: TRIS(4 7-DIPHENYL-1 10-PHENANTHROLINE)RU
• Synonyms: TRIS(4 7-DIPHENYL-1 10-PHENANTHROLINE)RU;Ru(dpp)3-PC;Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) bis(perchlorate)
• CAS NO: 75213-31-9
• Molecular Formula: 3C24H16N2.2ClO4.Ru
• Molecular Weight: 1297.18
• Product Categories: Biochemicals and Reagents;Luminescent Compounds/Detection;Stains and Dyes
• Mol File: 75213-31-9.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 543.1°C at 760 mmHg
• Flash Point: 242.1°C
• Appearance: /
• Vapor Pressure: 2.63E-11mmHg at 25°C
• Storage Temp.: Hygroscopic, -20°C Freezer, Under inert atmosphere
• Solubility: Acetonitrile (Slightly), Chloroform (Slightly), DMSO (Slightly), Methanol (Sligh
• Stability: Hygroscopic
• CAS DataBase Reference: TRIS(4 7-DIPHENYL-1 10-PHENANTHROLINE)RU(CAS DataBase Reference)
• NIST Chemistry Reference: TRIS(4 7-DIPHENYL-1 10-PHENANTHROLINE)RU(75213-31-9)
• EPA Substance Registry System: TRIS(4 7-DIPHENYL-1 10-PHENANTHROLINE)RU(75213-31-9)

Safety Data

• WGK Germany: 3
• F: 10-21
• Hazardous Substances Data: 75213-31-9(Hazardous Substances Data)

Usage

Uses

Tetramethylrhodamine isothiocyanate mixed isomers is an amino-reactive labeling reagent.

InChI:InChI=1/3C24H16N2.2ClHO4.Ru/c3*1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;2*2-1(3,4)5;/h3*1-16H;2*(H,2,3,4,5);/q;;;;;+2/p-2

Upstream product

• 1662-01-7 bathophenanthroline 
• 10049-08-8 ruthenium(III)chloride 

Relevant articles and documents

Stereochemical Effects on Monolayer Formation of (2+) (dpp = 4,7-Diphenyl-1,10-phenanthroline) at an Air-Water Interface

Stereochemical effects on monolayer formations have been studied at an air-water interface for the racemic mixture and enantiomer of (ClO4)2 (dpp = 4,7-diphenyl-1,10-phenanthroline).Stearic acid (SA) was added to reduce the cohesive interaction of the Ru(II) complexes.The ration of SA to Ru(II) complex, /, was varied from 0 to 4.At / = 0 and 1, the lift-off area per molecule at which the surface pressure increased from zero was smaller for the racemic mixture than for the enantiomer.The results indicated that the racemic mixture of the Ru(II) complex formed a more compact monolayer than the enantiomer.There was no difference observed in the surface pressure-molecular area (?-A) curves at / larger than 3.The monolayer was transferred onto a hydrophobic glass or silicon wafer substrate as a Langmuir-Blodgett (LB) film of Y-type.At / = 1, the d(001) spacing of the film was determined by X-ray diffraction measurements, leading to d(001) = 50.4 and 37.8 Angstroem for the racemic mixture and the enantiomer, respectively.The IR reflection-adsorption spectroscopy showed that the alkyl chains of SA molecules took different orientations for the racemic and enantiomeric films.It is postulated that SA molecules which intervened between the Ru(II) complexes are more perpendicular to the substrate surface due to the closer packing of the racemic Ru(II) complexes than the enantiomers.