75214-93-6

Basic information

• Product Name: Rhodium(1+), carbonyl(2-propanone)bis(triphenylphosphine)-,perchlorate
• Synonyms: Rhodium(1+), carbonyl(2-propanone)bis(triphenylphosphine)-,perchlorate
• CAS NO: 75214-93-6
• Molecular Formula: C40H36O2P2Rh.ClO4
• Molecular Weight: 813.028
• Mol File: 75214-93-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Rhodium(1+), carbonyl(2-propanone)bis(triphenylphosphine)-,perchlorate(CAS DataBase Reference)
• NIST Chemistry Reference: Rhodium(1+), carbonyl(2-propanone)bis(triphenylphosphine)-,perchlorate(75214-93-6)
• EPA Substance Registry System: Rhodium(1+), carbonyl(2-propanone)bis(triphenylphosphine)-,perchlorate(75214-93-6)

Safety Data

• Hazardous Substances Data: 75214-93-6(Hazardous Substances Data)

Upstream product

• 15318-33-9 chlorocarbonylbis(triphenylphosphine)rhodium(I) 

Downstream Products

• 84190-63-6 [Rh(CO)(OP(CH₃C₆H₄)3)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(OP(CH₃C₆H₄)3)(P(C₆H₅)3)2]ClO₄ 
• 108792-77-4 [(C₆H₄C₆H₂F₄)Rh(C₅H₄NNC₅H₄N)Rh(CO)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[(C₆H₄C₆H₂F₄)Rh(C₅H₄NNC₅H₄N)Rh(CO)(P(C₆H₅)3)2]ClO₄ 
• 110681-64-6 [Rh₃(C₈H₅N₂O)2(CO)4(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh₃(C₈H₅N₂O)2(CO)4(P(C₆H₅)3)2]ClO₄ 
• 25300-57-6 Rh(CO)(C₁₂H₈N₂)(P(C₆H₅)3)2⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(C₁₂H₈N₂)(P(C₆H₅)3)2]ClO₄ 
• 84190-73-8 [Rh(CO)(CH₃OC₅H₄NO)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(CH₃OC₅H₄NO)(P(C₆H₅)3)2]ClO₄ 
• 84190-67-0 [Rh(CO)(OAs(C₆H₅)3)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(OAs(C₆H₅)3)(P(C₆H₅)3)2]ClO₄ 
• 84190-61-4 [Rh(CO)(OP(C₆H₅)3)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(OP(C₆H₅)3)(P(C₆H₅)3)2]ClO₄ 
• 84190-71-6 [Rh(CO)(CH₃C₅H₄NO)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(CH₃C₅H₄NO)(P(C₆H₅)3)2]ClO₄ 
• 84190-65-8 [Rh(CO)(OP(CH₃OC₆H₄)3)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(OP(CH₃OC₆H₄)3)(P(C₆H₅)3)2]ClO₄ 
• 84190-59-0 [Rh(CO)(OP(ClC₆H₄)3)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(OP(ClC₆H₄)3)(P(C₆H₅)3)2]ClO₄ 

Relevant articles and documents

Rhodium(I) Complexes of 8-Methyl-, 8-Ethyl-, and 8-Isopropyl-quinolines and Realated 2-Substituted Derivatives

The complexes have been prepared from on adding unidentate L (8-methyl-, -ethyl-, or -isopropyl-quinoline) or bidentate L (1,10-phenantroline or quinoline-2-carboxaldehide-N-methylimine). 8-Alkyl-substitution of the latter ligand gives the complexes as isomers with uni- and bi-dentate L respectively with relative stabilities of the unidentate form depending on the 8-substituent in the order Pri > Et > Me.Unidentate L is also favoured by replacing PPh3 by P(C6H11)3 but bidentate co-ordination is found using AsPh3 or PMe2Ph.Equilibrium constants for chloro-bridge cleavage of by 8-substituted and 2,8-disubstituted quinolines are reduced by increasing the size of the 8-susbtituent and even more by further introduction of a 2-methyl group.The contributions of distortions in the co-ordination to these changes in equilibrium constants are discussed.