75295-59-9Relevant academic research and scientific papers
Benzosiloxaboroles: Silicon Benzoxaborole Congeners with Improved Lewis Acidity, High Diol Affinity, and Potent Bioactivity
Brzozowska, Aleksandra,?wik, Pawe?,Durka, Krzysztof,Kli?, Tomasz,Laudy, Agnieszka E.,Luliński, Sergiusz,Serwatowski, Janusz,Tyski, Stefan,Urban, Mateusz,Wróblewski, Wojciech
, p. 2924 - 2932 (2015)
(Figure Presented). The synthesis and physicochemical properties of benzosiloxaboroles, the silicon analogues of an important class of heterocyclic compounds - benzoxaboroles - is presented. They were prepared by halogen-lithium exchange reactions of (2-b
Silylaryl Halides Can Replace Triflates as Aryne Precursors
Mesgar, Milad,Daugulis, Olafs
supporting information, p. 3910 - 3913 (2016/08/16)
Silylaryl bromides and iodides can be prepared in one step from commercially available starting materials. Arynes can be generated from these compounds under conditions nearly identical to those employed for silylaryl triflates. Three distinct transformat
CONDENSED CYCLIC COMPOUND, AND ORGANIC LIGHT EMITTING DEVICE INCLUDING THE SAME
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Paragraph 1178, (2016/10/08)
Disclosed are a condensed ring compound and an organic light emitting device comprising the condensed ring compound. The organic light emitting device comprises: a first electrode; a second electrode facing the first electrode; and an organic layer interposed between the first electrode and the second electrode, wherein the organic layer comprises the condensed ring compound.COPYRIGHT KIPO 2015
Method of producing an o-disubstituted aromatic compound, and method of producing a monosubstituted-monohaloaromatic compound
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Page/Page column 17, (2008/12/07)
A method of producing an o-disubstituted aromatic compound, containing: continuously conducting at least the following steps (a) to (d): (a) a step of mono-lithiating one halogen atom of an o-dihaloaromatic compound, using a first microreactor; (b) a step of making the thus-obtained monolithiated product to react with an electrophilic compound, using a second microreactor, to obtain a monosubstituted-monohaloaromatic compound; (c) a step of lithiating the other halogen atom of the o-dihaloaromatic compound, using a third microreactor; and (d) a step of making the thus-obtained lithiated product successively to react with an electrophilic compound, using a forth microreactor.
THE SYNTHESIS AND REACTIONS OF ortho BROMOPHENYLLITHIUM
Chen, Loomis S.,Chen, Grace J.,Tamborski, Christ
, p. 283 - 292 (2007/10/02)
Experimental conditions have now been developed whereby o-bromophenyl-lithium(II) may be prepared in excellent yields and used as an organometallic intermediate for the synthesis of a variety of ortho bromo substituted phenyl compounds (o-BrC6H4X).The thermal stability, decomposition products and reactions of II were studied.Reactions between II and a variety of substrates, e.g., CO2, dimethylformamide, fluorinated esters, hexafluorobenzene, and organosilicon chlorides were examined.
