75405-15-1Relevant academic research and scientific papers
Oxidatively Assisted Nucleophilic Substitution of Organosilicon Iodides
Al-Wassil, Abdulaziz I.,Eaborn, Colin,Saxena, Anil K.
, p. 974 - 975 (1983)
The iodides (Me3Si)3CSiMe2I, (Me3Si)3CSiPh2I, and But3SiI react with m-chloroperbenzoic acid to give the hydroxides (Me3Si)3CSiMe2OH, (Me3Si)2C(SiPh2Me)(SiMe2OH), and But3SiOH, respectively, in MeOH alone, and the corresponding chlor
THE REACTIONS OF TRIS(TRIMETHYLSILYL)SILICON IODIDES AND HYDRIDES WITH IODINE MONOCHLORIDE
Eaborn, Colin,Hopper, Steven P.
, p. 27 - 32 (1980)
The compounds TsiSiPh2I and TsiSiMeClI (Tsi = (Me3Si)3C) have been found to react readily with ICl with rearrangement to give (Me3Si)2C(SiMe2Cl)-(SiPh2Me) and (Me3Si)2C(SiMe2Cl)2, respectively.The compounds TsiSiEt2I and TsiSiEtMeI give approximately 25 a
1,3-Migration of a phenyl group in the conversion of (Me3Si)2(PhMe2Si)CSiMePhX into (Me3Si)2(Ph2MeSi)CSiMe2Y species
Eaborn, Colin,Kowalewska, Anna,Stanczyk, Wlodzimierz
, p. 41 - 46 (2007/10/03)
The finding that compounds of the type (Me3Si)2(PhMe2Si)CSiMePhX react with electrophiles to give very predominantly rearranged products (Me3Si)2(Ph2MeSi)CSiMe2Y, which would be
Anchimeric assistance in the reactions of the crowded organosilicon iodide (Me3Si)2(Ph2MeSi)CSiMe2I with electrophiles
Al-Gurashi, Mohammad A. M. R.,Ayoko, G. Adefikayo,Eaborn, Colin,Lickiss, Paul D.
, p. 517 - 521 (2007/10/02)
The relative reactivities of the iodides (Me3Si)2(Ph2MeSi)CSiMe2I, 1, (Me3Si)2(PhMe2Si)CSiMe2I, 2, (Me3Si)3CSiPhMeI 3, (Me3Si)3CSiPh2I, 4, and (Me3Si)3CSiMe2I, 5, towards silver salts or ICl have been studied and the results support the proposal that for
