Oxidatively Assisted Nucleophilic Substitution of Organosilicon Iodides

DOI: 10.1039/c39830000974

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 974 - 975 (1983)

Update date:2022-08-10

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Authors:

Al-Wassil, Abdulaziz I.

Eaborn, Colin

Saxena, Anil K.

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Article abstract of DOI:10.1039/c39830000974

The iodides (Me3Si)3CSiMe2I, (Me3Si)3CSiPh2I, and Bu^t3SiI react with m-chloroperbenzoic acid to give the hydroxides (Me3Si)3CSiMe2OH, (Me3Si)2C(SiPh2Me)(SiMe2OH), and Bu^t3SiOH, respectively, in MeOH alone, and the corresponding chlor

Full text of DOI:10.1039/c39830000974

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