77548-00-6

Upstream product

• 1066-35-9 dimethylmonochlorosilane 
• 15816-05-4 (dichloromethyl)methylbis(trimethylsilyl)silane 
• 591-51-5 phenyllithium 
• 1631-82-9 chloro(methyl)phenylsilane 
• 212064-80-7 C₂₂H₃₈Si₄ 
• 115764-86-8 [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene 
• 15951-41-4 bis(trimethylsilyl)dichloromethane 
• 17739-53-6 di-phenylmethylsilyl fluoride 
• 75405-15-1 C₂₂H₃₇ClSi₄ 

Downstream Products

• 131531-22-1 C₂₂H₃₇BrSi₄ 
• 78752-28-0 (iododimethylsilyl)bis(trimethylsilyl)(methyldiphenylsilyl)methane 

Relevant academic research and scientific papers

Reaction of the (dichloromethyl)oligosilanes R(Me3Si)2Si - CHCl2 (R = Me, Ph, Me3Si) with organolithium reagents and the synthesis of novel kinetically stabilized silenes

The dichloromethyloligosilanes R1(Me3Si)2Si - CHCl2 (1a,b) (1a: R1 = Me; 1b: R1 = Ph), prepared by treatment of methylbis(trimethylsilyl)silane or phenylbis(trimethylsilyl)silane respective

1,3-Migration of a phenyl group in the conversion of (Me3Si)2(PhMe2Si)CSiMePhX into (Me3Si)2(Ph2MeSi)CSiMe2Y species

The finding that compounds of the type (Me3Si)2(PhMe2Si)CSiMePhX react with electrophiles to give very predominantly rearranged products (Me3Si)2(Ph2MeSi)CSiMe2Y, which would be

Anchimeric assistance in the reactions of the crowded organosilicon iodide (Me3Si)2(Ph2MeSi)CSiMe2I with electrophiles

The relative reactivities of the iodides (Me3Si)2(Ph2MeSi)CSiMe2I, 1, (Me3Si)2(PhMe2Si)CSiMe2I, 2, (Me3Si)3CSiPhMeI 3, (Me3Si)3CSiPh2I, 4, and (Me3Si)3CSiMe2I, 5, towards silver salts or ICl have been studied and the results support the proposal that for

STERICALLY-HINDERED ORGANOSILICON PERCHLORATES

The prechlorates (Me3Si)3C(SiMe2OClO3) and (Me3Si)2C(SiPh2Me)(SiMe2ClO3) have been obtained by treatment of the iodides (Me3Si)3C(SiMe2I) and (Me3Si)3C(SiPh2I), respectively, with AgClO4 in CH2Cl2.The perchlorates react with MeOH to give the methoxides (M