75420-24-5

Upstream product

• 31355-55-2 trichlorotris(tetrahydrofuran)molybdenum(III) 
• 23582-02-7 bis(2-diphenylphosphinoethyl)phenylphosphine 
• 89709-79-5 {MoCl₂(C₆H₅P(CH₂CH₂P(C₆H₅)2)2)(P(C₆H₅)3)} 
• 603-35-0 triphenylphosphine 
• 75365-55-8 MoCl₃(triphos) 
• 7727-37-9 nitrogen 

Downstream Products

• 173467-75-9 Mo(η(5)-C5H5)(H)(Ph(CH2CH2PPh2)2) 
• 1264241-23-7 [MoH(PhP(CH₂CH₂PPh₂)2)(acrylate)(triphenylphosphine)] 
• 144472-63-9 [Mo(η(6)-C6H5PPh2)(Ph(CH2CH2PPh2)2)] 
• 74707-27-0 MoBr₃(C₆H₅P(C₂H₄P(C₆H₅)2)2) 
• 302-01-2 hydrazine 
• 7664-41-7 ammonia 
• 75365-55-8 MoCl₃(triphos) 
• 7727-37-9 nitrogen 
• 178383-88-5 MoI₃((C₆H₅)P(CH₂CH₂P(C₆H₅)2)2) 
• 85993-39-1 [MoCl(NNH₂)(PhP(CH₂CH₂PPh₂)2)(PPh₃)]Cl 
• 98975-08-7 [MoBr(NNH₂)(PhP(CH₂CH₂PPh₂)2)(PPh₃)]Br 
• 74707-27-0 MoBr₃(C₆H₅P(CH₂CH₂P(C₆H₅)2)2) 

Relevant academic research and scientific papers

Kinetics and mechanism of molybdenum-mediated acrylate formation from carbon dioxide and ethylene

A zerovalent molybdenum complex, [(Ph2PCH2CH 2)2PPh]Mo(C2H4)(N2) 2, was found to promote coupling of CO2 and ethylene to afford a molybdenum(II) acrylate hy

Synthesis and characterization of low valent complexes of molybdenum containing the tridentate ligand PhP(CH2CH2PPh2)2(TRI)

Reduction of with sodium amalgam in the presence of potential ligands results in the formation of a series of new complexes containing η3-TRI.These include 6-C6H5R)(TRI) (where R = H, Me, MeO), 5-C5H5)(H)(TRI)>, (where R = Me, Et), and fac-.Protonation of the arene complexes results in the formation of both mono- and diprotonated complexes.Keywords: Molybdenum; Phosphine; Phosphite; Dinitrogen; η6-Benzene complex; η6-Arene complex.

Electrochemical Generation of Low-valent Molybdenum Tri-tertiary Phosphine Complexes: Interactions with Monophosphines and Molecular Nitrogen

The electrochemical reduction of the 15-electron molybdenum(III) complex , dpepp = Ph2PCH2CH2P(Ph)CH2CH2PPh2, has been studied in the presence of PPh3 under argon and under molecular nitrogen.The primary reduction of the trichloride involves a reversible single-electron transfer to give the unstable 16-electron molybdenum(II) anion -.Loss of chloride from this anion prior to or following further electron transfer provides two principal pathways to molybdenum(0) products, 6-C6H5PPh2)(dpepp)> under Ar or cis- under molecular nitrogen, a relatively high potential via molybdenum(I) solvated intermediates and a low potential pathway via trans-.The cis-dinitrogen complex is unstable on the preparative timescale, small amounts of trans- are formed, presumably by isomerisation, but the major product is the η6-arene complex.

Modification of silicon and carbon electrodes with methacrylamide polymers containing covalently attached molybdenum dinitrogen complexes

Methacrylamide polymers with pendant monodentate, bidentate, and tridentate phosphine ligands (poly-P1, poly-P2, and poly-P3, respectively) have been synthesized. These polymers react with Mo(N2)2(PPh2Me)4 to form polymers with bound molybdenum dinitrogen complexes. Similarly, MoCl3(THF)3 reacts with poly-P3 to form MoCl3(poly-P3). These polymers have been used to modify silicon and carbon electrodes. These electrodes have been characterized by cyclic voltammetry and FT-IR spectroscopy. The redox chemistry of electrodes modified with Mo(N2)2(poly-P3)PPh2Me and Mo(N2)2(poly-P2)2 on silicon and carbon electrodes closely parallels that observed for their solution counterparts. However, reduction of MoCl3(poly-P3) and MoCl3(poly-P2)2 on silicon and carbon electrodes does not lead to formation of polymer-bound molybdenum dinitrogen complexes.