75420-75-6Relevant academic research and scientific papers
Hypervalent iodine reagent mediated diamination of [60]fullerene with sulfamides or phosphoryl diamides
Yang, Hai-Tao,Lu, Xin-Wei,Xing, Meng-Lei,Sun, Xiao-Qiang,Miao, Chun-Bao
supporting information, p. 5882 - 5885 (2015/02/19)
A hypervalent iodine-promoted intermolecular diamination reactions of C60 with sulfamides or phosphoryl diamides affords two classes of novel C60-fused cyclic sulfamide or phosphoryl diamide derivatives. The reaction between C60 and sulfamides can be effectively controlled to selectively synthesize diamination products or azafulleroids under PhIO/I2 or PhI(OAc)2/I2 conditions, respectively. Moreover, phosphoryl diamides were first used as an amine source in the diamination of alkenes.
