75456-59-6Relevant academic research and scientific papers
Do the electronic effects of sulfur indeed control the π-selectivity of γ-sulfenyl enones? An investigation
Yadav, Veejendra K.,Babu, K. Ganesh,Parvez, Masood
, p. 3866 - 3874 (2007/10/03)
The electronic effects of sulfur in γ-sulfenyl enones are not transmitted to the carbonyl carbon through the π bond as reported previously. The diastereoselectivity is rather controlled by a combination of several other factors. The steric effects arising
A novel synthesis of α-(phenylthio)aldehydes
Jansen, B. J. M.,Peperzak, R. M.,Groot, Ae. de
, p. 489 - 494 (2007/10/02)
Addition of methoxy(phenylthio)methyllithium to ketones, followed by rearrangement of the adducts, provides a new method for the preparation of α-(phenylthio)aldehydes.The rearrangement is stereospecific.
A NOVEL SYNTHESIS OF α-SULFENYLATED ALDEHYDES
Groot, Ae. de,Jansen, B. J. M.
, p. 887 - 888 (2007/10/02)
Ketones are converted into α-sulfenylated aldehydes with addition of one carbon atom via reaction with methoxyphenylthiomethyllithium followed by rearrangement of the adducts.
ELONGATION OF CARBONYL COMPOUNDS BY UTILIZING ELECTROREDUCTION AS A KEY STEP
Shono, Tatsuya,Matsumura, Yoshihiro,Kashimura, Shigenori
, p. 1545 - 1548 (2007/10/02)
This transformation of aldehydes, ketones and esters to the next higher homologous aldehydes was accomplished by utilizing electroreductive 1,2-elimination as a key step.
