75482-37-0

Basic information

• Product Name: (R,S)-1,2-bis(hydridophenylphosphoryl)ethane
• CAS NO: 75482-37-0
• Molecular Weight: 278.227
• Mol File: 75482-37-0.mol

Chemical Properties

• CAS DataBase Reference: (R,S)-1,2-bis(hydridophenylphosphoryl)ethane(CAS DataBase Reference)
• NIST Chemistry Reference: (R,S)-1,2-bis(hydridophenylphosphoryl)ethane(75482-37-0)
• EPA Substance Registry System: (R,S)-1,2-bis(hydridophenylphosphoryl)ethane(75482-37-0)

Safety Data

• Hazardous Substances Data: 75482-37-0(Hazardous Substances Data)

Upstream product

• 18899-64-4 1,2-Bis(phenylphosphino)ethane 
• 90826-86-1 Tetra-n-butylammonium-phenylcyanphosphid 
• 2946-59-0 dicyano(phenyl)phosphine 
• 90826-98-5 dicyanophenylphosphinoethane 
• 116997-13-8 Isopropyl Ethylenebis(phosphinate) 

Downstream Products

• 343620-83-7 {[2-(Hydroxymethyl-phenyl-phosphinoyl)-ethyl]-phenyl-phosphinoyl}-methanol 
• 73191-45-4 Hydroxy-({2-[(1-hydroxy-2-oxo-ethyl)-phenyl-phosphinoyl]-ethyl}-phenyl-phosphinoyl)-acetaldehyde 
• 73191-44-3 C₂₈H₂₆N₂O₂P₂S₂ 
• 75502-83-9 C₂₀H₃₂O₂P₂Si₂ 
• 177423-64-2 [Pt(OP(C₆H₅)CH₂CH₂P(C₆H₅)O)]4 
• 3071-34-9 benzyl hydroperoxide 
• 100-51-6 benzyl alcohol 
• 100-52-7 benzaldehyde 
• 73191-48-7 1-(Diphenyl-phosphinoyl)-2-[(2-{[2-(diphenyl-phosphinoyl)-1,2-dihydroxy-ethyl]-phenyl-phosphinoyl}-ethyl)-phenyl-phosphinoyl]-ethane-1,2-diol 
• 73191-49-8 1-(Dibutyl-phosphinoyl)-2-[(2-{[2-(dibutyl-phosphinoyl)-1,2-dihydroxy-ethyl]-phenyl-phosphinoyl}-ethyl)-phenyl-phosphinoyl]-ethane-1,2-diol 
• 75502-89-5 C₂₂H₃₆I₂O₂P₂Si₂⁽²⁺⁾*2I^(1-) 
• 75502-86-2 C₂₂H₃₈O₂P₂Si₂⁽²⁺⁾*2I^(1-) 
• 73191-43-2 C₄₀H₃₈N₂O₂P₂ 
• 73191-50-1 2-acetoxy-2-methyl-1,3-diphenyl-[1,3]diphospholane 1,3-dioxide 

Relevant articles and documents

Palladium-Catalyzed Synthesis of Bis(phosphinates) and Bis(phosphine Oxides) with Tetra- and Hexamethylene Bridges

Some aryl-substituted bis(phosphinates) and bis(phosphine oxides) with tetra- and hexamethylene bridges, which are not easily accessible by conventional chemical methods, were synthesized by palladium-catalyzed formation of the carbon-phosphorus bond.

Degradation of (PhP)5 by Cyanide: Formation, Structure, and Reactions of the Phenyl Cyanophosphide Ion

Phenyl cyanophosphide PhPCN- is formed in the ractions of P(CN)2- with phenyllithium and of PhP(CN)2 with CN-, and it may be prepared by nucleophilic degradation of (PhP)5 with ammonium or phosphonium cyanides.With sulfur it yields phenyl cyanodithiophosphinates 4, by alkylation alkyl(phenyl)cyanophosphanes 6 and by hydrolysis of the latter alkyl(phenyl)phosphine oxides 7. - The molecular structure of PhPCN (3c) as determined by X-ray analysis shows an almost planar anion with 102 deg CPC angle.A long PC and short CN bond in the PCN group make PhPCN- appear as "cyanide complex of phenylphosphinidene".