90826-86-1

Upstream product

• 2946-59-0 dicyano(phenyl)phosphine 
• 10442-39-4 tetra-n-butylammonium cyanide 
• 3376-52-1 pentaphenylcyclopentaphosphane 

Downstream Products

• 311-28-4 tetra-(n-butyl)ammonium iodide 
• 90826-93-0 C₁₃H₁₆NP 
• 90826-92-9 C₁₁H₁₄NP 
• 90826-96-3 C₁₁H₁₂NO₂P 
• 4791-48-4 diphenylcyanophosphine 
• 1101-41-3 Tetraphenyldiphosphin 
• 1104-52-5 tetraphenyl-cyclotetraphosphane 
• 3376-52-1 pentaphenylcyclopentaphosphane 
• 90826-98-5 dicyanophenylphosphinoethane 
• 90826-95-2 C₁₀H₁₀NOP 
• 90826-91-8 Methyl(phenyl)cyanphosphan 
• 75482-37-0 1,2-bis(hydridophenylphosphoryl)ethane 
• 20335-96-0 (±)-n-butyl(phenyl)phosphine oxide 
• 21162-08-3 (±)-ethyl(phenyl)phosphine oxide 

Relevant academic research and scientific papers

Phosphinocyclopentadienide via Cyclopentadienylphosphide

Lithiumorganyls RLi (R = Me, Bu, Ph) add to (PhP)5 in successive degradation and disproportionation equilibria depending on the ratio of the reactants.At -70 deg C (R = Me) disproportionation is blocked and (PhP)4R(-) and (PhP)3R(-) can be detected.With excess RLi monophosphides PhPR(-) are formed.CpNa with the help of a crown ether degrades (PhP)5 or substitutes cyanide from PhPCN(-) to give an equilibrium mixture of (PhP)nCp(-) anions, which stabilize by proton shifts: In case of n = 1 and 2 a shift from the Cp unit to the terminal phosphorus results in the formation of the phenylphosphino- and diphenyldiphosphino-cyclopentadienide anion, in case of n = 3 two proton shifts within the Cp unit result in a cyclopenteno-1,2,3-triphospholene allylic anion. - Keywords: Cyclophosphane, Cyclopentadienide, Nucleophilic Degradation, 31P NMR Spectra

Degradation of (PhP)5 by Cyanide: Formation, Structure, and Reactions of the Phenyl Cyanophosphide Ion

Phenyl cyanophosphide PhPCN- is formed in the ractions of P(CN)2- with phenyllithium and of PhP(CN)2 with CN-, and it may be prepared by nucleophilic degradation of (PhP)5 with ammonium or phosphonium cyanides.With sulfur it yields phenyl cyanodithiophosphinates 4, by alkylation alkyl(phenyl)cyanophosphanes 6 and by hydrolysis of the latter alkyl(phenyl)phosphine oxides 7. - The molecular structure of PhPCN (3c) as determined by X-ray analysis shows an almost planar anion with 102 deg CPC angle.A long PC and short CN bond in the PCN group make PhPCN- appear as "cyanide complex of phenylphosphinidene".