75498-68-9Relevant academic research and scientific papers
Alkylation of Ketoxime with Dichloromethane Using Bases under Phase-transfer Conditions. Formation of Methylene Dioxime and Novel Heteromacrocyclic Compounds
Hosokawa, Takahiro,Ohta, Toshiyuki,Okamoto, Yoshihiro,Murahashi, Shun-Ichi
, p. 194 - 200 (1985)
Ketoximes, when treated with KO2 (1 equiv) in the presence of di-μ-chlorobis(2-methylallyl)dipalladium-(II) (0.1 equiv per Pd) in dichloromethane , give methylene dioximes in moderate yields.This alkylation of ketoximes with CH2Cl2 is also promoted by the
A green protocol for synthesis of methylene dioximes promoted by an ionic liquid [bmim]BF4
Zang, Hongjun,Zhang, Yong,Wang, Meiling,Cheng, Bo-Wen
experimental part, p. 465 - 467 (2010/02/28)
The ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate, [bmim]BF4, has been demonstrated to be an effective catalyst for synthesis of methylene dioximes. These reactions proceed with excellent yields under shorter reaction times than ot
A simple method for synthesis of methylene dioximes using poly(ethylene glycol)-400 as a phase transfer catalyst
Shedge, Aarti S.,Kavitake, Bhanudas P.,Desai, Uday V.,Wadgaonkar, Prakash P.
, p. 4483 - 4486 (2007/10/03)
A simple method for synthesis of methylene dioximes by reaction of ketoximes with dichloromethane in the presence of aqueous sodium hydroxide solution using poly (ethylene glycol)-400 (PEG-400) as a phase transfer catalyst is described.
Pd(II)-catalyzed condensation reaction of ketoximes and dichloromethane using potassium superoxide
Hosokawa, Takahiro,Ohta, Toshiyuki,Okamoto, Yoshihiro,Murahashi, Shun-Ichi
, p. 1259 - 1260 (2007/10/02)
Methylene dioximes are formed from ketoximes and CH2Cl2 using either KO2 with a catalytic amount of Pd(II) complex 3 or K2CO3 with 18-crown-6 catalyst. The reactivity of ketoximes towards CH2/su
