Alkylation of Ketoxime with Dichloromethane Using Bases under Phase-transfer Conditions. Formation of Methylene Dioxime and Novel Heteromacrocyclic Compounds

DOI: 10.1246/bcsj.58.194

Source and publish data:

Bulletin of the Chemical Society of Japan p. 194 - 200 (1985)

Update date:2022-07-29

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Authors:

Hosokawa, Takahiro

Ohta, Toshiyuki

Okamoto, Yoshihiro

Murahashi, Shun-Ichi

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Article abstract of DOI:10.1246/bcsj.58.194

Ketoximes, when treated with KO2 (1 equiv) in the presence of di-μ-chlorobis(2-methylallyl)dipalladium-(II) (0.1 equiv per Pd) in dichloromethane , give methylene dioximes in moderate yields.This alkylation of ketoximes with CH2Cl2 is also promoted by the

Full text of DOI:10.1246/bcsj.58.194

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