Alkylation of Ketoxime with Dichloromethane Using Bases under Phase-transfer Conditions. Formation of Methylene Dioxime and Novel Heteromacrocyclic Compounds

DOI: 10.1246/bcsj.58.194

Source and publish data:

Bulletin of the Chemical Society of Japan p. 194 - 200 (1985)

Update date:2022-07-29

Topics:

Authors:

Hosokawa, Takahiro

Ohta, Toshiyuki

Okamoto, Yoshihiro

Murahashi, Shun-Ichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.58.194

Ketoximes, when treated with KO2 (1 equiv) in the presence of di-μ-chlorobis(2-methylallyl)dipalladium-(II) (0.1 equiv per Pd) in dichloromethane , give methylene dioximes in moderate yields.This alkylation of ketoximes with CH2Cl2 is also promoted by the

Full text of DOI:10.1246/bcsj.58.194

Products guided by the article

Product name:Cyclohexanone, O,O'-methylenedioxime

Cas No:75498-68-9

R&D Labs maybe for 75498-68-9

Shanghai chemrole co.,ltd

Contact:021-50278900

Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china
NINGBO YINZHOU PRECISE COLOR CO.,LTD.

Contact:86-574-88139809 86-574-83033159

Address:Qiming Road,Yinzhou,Ningbo,China
ZHANGJIAGANG FREE TRADE ZONE YONG HAN INTERNATIONAL TRADING CO., LTD(expird)

Contact:86 512 57910558

Address:qianjin M road
LianYunGang Chiral Chemical(CHINA) CO.,LTD

Contact:+86-518-83616958 +86-519-82884848

Address:LianYunGang Chemical Industry Park (JiangSu)
Hubei anhuang chemical Co.Ltd

Contact:

Address:308# dongwu avenue dongxihu district wuhan city

Relevant to this article

SYNTHESIS OF LEPIOCHLORIN, AN ANTIBIOTIC METABOLITE OF A FUNGUS CULTIVATED BY ANTS

Doi:10.1016/S0040-4039(00)78602-3
(1980)
Synthesis, structure, spectral properties and DFT quantum chemical calculations of 4-aminoazobenzene dyes. Effect of intramolecular hydrogen bonding on photoisomerization

Doi:10.1016/j.saa.2016.12.005
(2017)
Electron ionization-induced fragmentation of N- and O-alkoxymethylated carbostyril and phenanthridinone

Doi:10.1002/jms.652
(2004)
Structures of BBM-928 A, B, and C. Novel Antitumor Antibiotics from Actinomadura luzonensis

Doi:10.1021/ja00395a054
(1981)
N-heterocycles scaffolds as quorum sensing inhibitors. Design, synthesis, biological and docking studies

Doi:10.3390/ijms21249512
(2020)
Phosphinohydrazines and phosphinohydrazides M(-N(R)-N(R) -PPh₂)_n of some transition and main group metals: Synthesis and characterization. Rearrangement of Ph₂ P-NR-NR- ligands into aminoiminophosphorane, RN=PPh₂-NR-, and related chemistry

Doi:10.1016/j.jorganchem.2004.06.056
(2004)

Article Doi