75498-69-0Relevant academic research and scientific papers
Alkylation of Ketoxime with Dichloromethane Using Bases under Phase-transfer Conditions. Formation of Methylene Dioxime and Novel Heteromacrocyclic Compounds
Hosokawa, Takahiro,Ohta, Toshiyuki,Okamoto, Yoshihiro,Murahashi, Shun-Ichi
, p. 194 - 200 (2007/10/02)
Ketoximes, when treated with KO2 (1 equiv) in the presence of di-μ-chlorobis(2-methylallyl)dipalladium-(II) (0.1 equiv per Pd) in dichloromethane , give methylene dioximes in moderate yields.This alkylation of ketoximes with CH2Cl2 is also promoted by the
Pd(II)-catalyzed condensation reaction of ketoximes and dichloromethane using potassium superoxide
Hosokawa, Takahiro,Ohta, Toshiyuki,Okamoto, Yoshihiro,Murahashi, Shun-Ichi
, p. 1259 - 1260 (2007/10/02)
Methylene dioximes are formed from ketoximes and CH2Cl2 using either KO2 with a catalytic amount of Pd(II) complex 3 or K2CO3 with 18-crown-6 catalyst. The reactivity of ketoximes towards CH2/su
