75499-91-1

Basic information

• Product Name: 2,5-anhydro-1,4-dideoxy-6-O-(p-tolylsulphonyl)-D-xylo-hexitol
• CAS NO: 75499-91-1
• Molecular Weight: 286.349
• Mol File: 75499-91-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 2,5-anhydro-1,4-dideoxy-6-O-(p-tolylsulphonyl)-D-xylo-hexitol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-anhydro-1,4-dideoxy-6-O-(p-tolylsulphonyl)-D-xylo-hexitol(75499-91-1)
• EPA Substance Registry System: 2,5-anhydro-1,4-dideoxy-6-O-(p-tolylsulphonyl)-D-xylo-hexitol(75499-91-1)

Safety Data

• Hazardous Substances Data: 75499-91-1(Hazardous Substances Data)

Upstream product

• 75499-82-0 2,5-anhydro-4,5-di-O-benzoyl-1,3-O-isopropylidene-D-glucitol 
• 111967-29-4 2,5-anhydro-3-O-benzoyl-1,4-dideoxy-D-gluco-heptitol 
• 111967-30-7 2,5-anhydro-3-O-benzoyl-1,4-dideoxy-D-xylo-hexitol 
• 82109-99-7 (2S,3S,5S)-5-hydroxymethyl-2-methyltetrahydrofuran-3-ol 
• 98-59-9 p-toluenesulfonyl chloride 
• 124251-97-4 (S)-2-(2-Benzyloxy-ethoxy)-propionic acid 
• 123990-91-0 (S)-5-Benzyloxymethyl-2-methyl-dihydro-furan-3-one 
• 75499-87-5 2,5-anhydro-4,6-di-O-benzoyl-1-chloro-1-deoxy-D-glucitol 
• 75499-89-7 2,5-anhydro-4,6-di-O-benzoyl-1-deoxy-D-ribo-hex-3-ulose 
• 75499-88-6 2,5-anhydro-4,6-di-O-benzoyl-1-deoxy-D-glucitol 
• 75499-85-3 2,5:3,4-dianhydro-1-O-p-tolylsulphonyl-D-allitol 
• 75499-90-0 2,5-anhydro-6-O-benzoyl-1,4-dideoxy-D-erythro-hex-3-ulose 
• 111967-29-4 2,5-anhydro-3-O-benzoyl-1,4-dideoxy-D-allo-heptitol 
• 112020-37-8 2,5-anhydro-3-O-benzoyl-1,4-dideoxy-D-ribo-hexitol 

Downstream Products

• 2303-35-7 (+)-muscarine chloride 
• 82083-43-0 (+)-muscarine toluene-p-sulfonate salt 
• 24570-49-8 (+)-muscarine iodide 
• 111967-25-0 L-(+)-epimuscarine toluene-p-sulphonate 

Relevant articles and documents

Blue light photoredox decarboxylation and tin-free Barton-McCombie reactions in the stereoselective synthesis of (+)-muscarine

Starting from a 1,2-O-isopropylidene-α-D-xylofuranose derivative, a non-toxic free-radical approach for the synthesis of (+)-muscarine is reported. To this end, a stereoselective allylation reaction at the anomeric position of a respective xylofuranose de

(+)-Muscarine From L-Rhamnose

A short synthesis of (+)-muscarine from L-rhamnose which does not require the use of any protecting group is described.

A Concise Enantioselective Synthesis of (+)-Muscarine from (R)-O-Benzylglycidol

A concise enantioselective synthesis of (+)-muscarine has been established via the novel formation of a 3,4-dihydrofuran starting from (R)-O-benzylglycidol.