82109-99-7Relevant articles and documents
Efficient chirality transfer in the Sml2-mediated cyclization of aldehydo β-alkoxyvinyl sulfoxides: Asymmetric synthesis of 3-hydroxyoxanes
Jung, Jae Hoon,Kim, Yong Wook,Kim, Min Ah,Choi, Soo Young,Chung, Young Keun,Kim, Tae-Rae,Shin, Seokmin,Lee, Eun
, p. 3225 - 3228 (2008/02/11)
Stereoselective syntheses of 3-hydroxyoxanes were achieved via efficient chirality transfer in the Sml2-mediated cyclization reactions of aldehydo β-alkoxyvinyl sulfoxides.
Practical chiral route to muscarine and its three diastereomers
Ohshiba,Yoshimitsu,Ogasawara
, p. 1067 - 1069 (2007/10/02)
A practical route to all possible stereoisomers of the muscarine alkaloids in optically pure forms has been developed starting from a readily accessible chiral starting material.
Dichloromethylenation of Sugar γ-Lactones: a Stereospecific Synthesis of L-(+)-Muscarine and L-(+)-Epimuscarine Toluene-p-sulphonates
Bandzouzi, Alphonse,Chapleur, Yves
, p. 661 - 664 (2007/10/02)
Treatment of di-isopropylidene-D-mannono-1,4-lactone (3) with hexamethylphosphorous triamide-tetrachloromethane gave the dichloro-olefin (4), which was converted into the ketone (5) by treatment with lithium di-isopropylamide.Reduction with Raney nickel g