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Usage

Uses

Used in Lubricant Industry:
Perfluorohexene-1 is used as a lubricant due to its high chemical stability and resistance to heat, which makes it ideal for applications requiring low friction and wear, especially in harsh environments.
Used in Surfactant Industry:
It serves as a surfactant, leveraging its unique properties to reduce surface tension in various solutions, which is beneficial in processes such as emulsification, wetting, and foaming.
Used in Chemical Production:
Perfluorohexene-1 is utilized as a precursor in the synthesis of other fluorine-containing compounds, contributing to the creation of a range of specialty chemicals and materials.
Used in Electronics and Semiconductor Industries:
It is being researched for potential applications in the electronics and semiconductor sectors, capitalizing on its unique electrical and dielectric properties that could enhance the performance of electronic devices and components.

InChI:InChI=1/C6F12/c7-1(2(8)9)3(10,11)4(12,13)5(14,15)6(16,17)18

Upstream product

• 116-15-4 perfluoropropylene 
• 122-60-1 Phenyl glycidyl ether 
• 355-43-1 n-perfluorohexyl iodide 
• 13709-36-9 xenon difluoride 
• 375856-42-1 perfluoro-trans-hex-1-enyldifluoroborane 
• 20109-59-5 perfluoroheptanoic acid sodium salt 

Downstream Products

• 2706-90-3 Perfluoropentanoic acid 
• 82943-30-4 C₁₂H₆F₁₀N₂ 
• 82943-29-1 2-hydroperfluorocaproyl fluoride phenylhydrazone 
• 82943-26-8 perfluoro-2-pentenoyl fluoride phenylhydrazone 
• 1582-32-7 F-hept-2-ene 
• 355-42-0 tetradecafluorohexane 
• 137730-99-5 1-phenylazo-2-hydroperfluoro-1-hexene 

Relevant academic research and scientific papers

A long the chain contains the fluorine process for the preparation of an olefin

The invention relates to a preparation method of long-chain fluorine-containing alkene. The preparation method comprises the following steps: (1) addition reaction: continuously introducing fluorine-containing monomers into a reactor with a perfluoroalkyl group iodine solution and a radical initiator contained, regulating the pressure difference of front and rear fluorine-containing monomers inside the reactor to control the flow rate of the fluorine-containing monomers, carrying out the addition reaction through a bubbling method, preparing an addition product, and after the reaction is finished, carrying out reduced pressure distillation to obtain the addition product with certain purity; and (2) elimination reaction: removing HI of the addition product under an alkaline condition to obtain a long-chain alkene product. The preparation method disclosed by the invention can be used for preparing the long-chain fluorine-containing alkene through two-step reaction, namely addition and removal, and by adopting perfluoroalkyl group iodine and the fluorine-containing monomers as raw materials, the method is high in selectivity, simple, environment-friendly and easy to implement.

The Reaction of 2-X-1,2-Difluoroalk-1-enyldifluoroboranes with Xenon Difluoride. A Methodical Approach to 1,2-Difluoroalk-1-enylxenon(II) Salts

2-X-1,2-Difluoroalk-1-enylxenon(II) salts were prepared by the reaction of XeF2 with XCF=CFBF2 (X = F, trans-H, cis-Cl, trans-Cl, cis-CF3, cis-C2F5) but no organoxenon(II) compounds were obtained when the trans-isomers of boranes, trans-XCF=CFBF 2 (X = CF3, C4F9, C 4H9, Et3Si), were used under similar conditions.

Transformations of F-Alkyl Iodides and Bromides Induced by Nickel(0) Carbonyl

Adducts of primary F-alkyl iodides with nickel carbonyl are formed readily in donor solvents and pyrolyze at 100-150 °C to give olefinic coupling products in high yield. The mechanism proposed to account for the observed chemistry involves preferential α-elimination of fluorine with formation of a carbenoid species complex coordinated to nickel. Differences in reaction paths among several types of substrate halides are rationalized on the basis of polarization of the Ni-C bond in the adducts. Support for these proposals is provided by state-of-the-art calculations.

REACTIVITE DES PERFLUOROHALOGENOALCANES EN PRESENCE DE COUPLES METALLIQUES. REACTIVITE DE PERFLUOROIODOALCANES SUR DES DERIVES HALOGENES DANS DES SOLVANTS APROTIQUES DISSOCIANTS (DMSO, DMF).

Perfluoroalkyl iodides (RFI) reacts with organic halide in dissociants solvents (DMF, DMSO) in the presence of zinc-copper couple through an organometallic route; in this way C6F13Cl, C6F13CH2CH2I, (C6F13)2Zn have been prepared.