75501-29-0Relevant academic research and scientific papers
Carbenoid chain reactions through proton, deuteron, or bromine transfer from unactivated 1-bromo-1-alkenes to organolithium compounds
Knorr, Rudolf,Pires, Claudio,Freudenreich, Johannes
, p. 6084 - 6090 (2008/02/09)
(Chemical Equation Presented) The deceptively simple vinylic substitution reactions Alk2C=CA-Br + RLi → Alk2C=CA-R + LiBr (A = H, D, or Br) occur via an alkylidenecarbenoid chain mechanism (three steps) without transition metal catal
On the Formation and Reactivity of Di-tert-alkyl Substituted Phenylalkenes
Knorr, Rudolf,Lattke, Ernst,Raepple, Edith
, p. 1207 - 1215 (2007/10/02)
Molecular rearrangements occur during the attempted syntheses of α-bromo-β,β-di-tert-alkylstyrenes; the resulting structures are elucidated.A hydrocarbon dimer with allenic structure accompanies the formation of the Grignard reagent from an α-bromostyrene
