75561-08-9Relevant academic research and scientific papers
Synchronous Skeletal Rearrangement of D-Nor-5α-androstane-16α- and -16β-carbonyl m-Chlorobenzoyl Peroxides
Suginome, Hiroshi,Uchida, Tsutomu
, p. 943 - 946 (1980)
The reaction of D-nor-5α-androstan-16β-carbonyl chloride, a steroidal cyclobutanecarbonyl chloride, with m-chloroperbenzoic acid leads via rearrangement to a C-homo-D-bisnor-steroid.In contrast, the 16α-isomer with m-chloroperbenzoic acid afforded the cor
Synthesis and Photoreaction of D-Nor-5α-androstan-16-one Acetylhydrazone in the Presence of Oxygen
Suginome, Hiroshi,Uchida, Tsutomu,Kizuka, Kazuhiko,Masamune, Tadashi
, p. 2285 - 2291 (2007/10/02)
D-Nor-5α-androstan-16-one was prepared via seven steps from 16-diazo-3β-hydroxyandrost-5-en-17-one.The major products of the photolysis of its acetylhydrazone in dioxane containing oxygen were the parent ketone and 17-oxa-5α-androstan-16-one, accompanied
