75561-10-3Relevant academic research and scientific papers
Synchronous Skeletal Rearrangement of D-Nor-5α-androstane-16α- and -16β-carbonyl m-Chlorobenzoyl Peroxides
Suginome, Hiroshi,Uchida, Tsutomu
, p. 943 - 946 (2007/10/02)
The reaction of D-nor-5α-androstan-16β-carbonyl chloride, a steroidal cyclobutanecarbonyl chloride, with m-chloroperbenzoic acid leads via rearrangement to a C-homo-D-bisnor-steroid.In contrast, the 16α-isomer with m-chloroperbenzoic acid afforded the cor
