75562-67-3Relevant academic research and scientific papers
Study of Mechanism of Reduction of 2-Bromo-1-(p-X-phenyl)ethylidenemalonitrile by 1-Benzyl-1,4-dihydronicotinamide and 10-Methyl-9,10-dihydroacridine
Liu, You-Cheng,Li, Bin,Guo, Qing-Xiang
, p. 9671 - 9680 (2007/10/02)
The reduction of 2-bromo-1-(p-X-phenyl)ethylidenemalonitrile (X-BPM: X=H, F, Cl, Br, CN) by NADH models BNAH and AcrH2 has been investigated.Based on product analysis, kinetic isotope effect, and free energy relationship, a direct hydride transfer and an
Formation of Cyclopropanes from 2-Bromo-1-phenylalkylidenemalononitriles and Nucleophiles
Berg, Arne,Kolsaker, Per
, p. 289 - 294 (2007/10/02)
The reaction of the title compounds with selected nucleophiles was studied.With cyanide and hydride (from sodium borohydride) ions, substituted cyclopropanes were obtained in good yields.With alkoxide ions, cyclopropanes were formed only when the bromide
