75712-53-7

Upstream product

• 75712-52-6 3-benzoylamino-2,3,6-trideoxyhexono-L-arabino-δ-lactone 
• 98-88-4 benzoyl chloride 
• 99630-06-5 t-butyl (4S,5S,2Z)-3-amino-4,5-(cyclohexylidenedioxy)-2-hexenoate 
• 90819-77-5 t-butyl (3S,4S,5S)-3-acetamido-4,5-(cyclohexylidenedioxy)hexanoate 
• 90865-23-9 t-butyl (4S,5S,2Z)-3-acetamido-4,5-(cyclohexylidenedioxy)-2-hexenoate 
• 75712-55-9 (-)-xylo-3-(Benzoylamino)-2,3,6-trideoxyhexanoic acid γ-lactone 
• 75712-56-0 (3S,4R,5S)-arabino-3-benzoylamino-2,3,6-trideoxyaldonic acid γ-lactone 
• 75765-34-3 (E)-3-((4R,5S)-2,2,5-Trimethyl-[1,3]dioxolan-4-yl)-acrylic acid ethyl ester 

Downstream Products

• 81176-31-0 N-Benzoyl-L-daunosamine 

Relevant academic research and scientific papers

A New Synthesis of 3-Amino-2-alkenoates. Novel Synthetic Route to Amino Sugars N-benzoyl-L-daunosamine and -L-acosamine

Alkanoate esters are found to couple with various nitriles to give (Z)-3-amino-2-alkenoates in good yields with the aid of a magnesium amide prepared by the reaction of ethylmagnesium bromide and diisopropylamine.The C-C bond forming reaction was applied

A STEREOSELECTIVE SYNTHESIS OF N-BENZOYL L-DAUNOSAMINE

Reaction of (2S,3S)-2,3-(cyclohexylidenedioxy)butanenitrile, derived from L(+)-tartrate or (S)-lactate, with the magnesium enolate of t-butyl acetate gave the corresponding (Z)-β-amino acrylate derivative, which was in turn transformed into N-benzoyl L-da

Synthesis of N-Trifluoroacetyl-L-acosamine and -L-daunosamine

N-Trifluoroacetyl-L-acosamine (18) has been chirally synthesised from the chiral educt (1) obtained from cinnamaldehyde and bakers' yeast, whereas N-trifluoroacetyl-L-daunosamine (17) was obtained by inverting the configuration at C-4 of the intermediate