75712-52-6

Upstream product

• 75765-34-3 (E)-3-((4R,5S)-2,2,5-Trimethyl-[1,3]dioxolan-4-yl)-acrylic acid ethyl ester 
• 75712-56-0 (3S,4R,5S)-arabino-3-benzoylamino-2,3,6-trideoxyaldonic acid γ-lactone 
• 75712-55-9 (-)-xylo-3-(Benzoylamino)-2,3,6-trideoxyhexanoic acid γ-lactone 
• 90400-03-6 t-butyl (3S,4R,5S)-3-acetamido-4,5-(cyclohexylidenedioxy)hexanoate 
• 98-88-4 benzoyl chloride 
• 90400-02-5 t-butyl (4R,5S,2Z)-3-acetamido-4,5-(cyclohexylidenedioxy)-2-hexenoate 
• 90400-01-4 t-butyl (4R,5S,2Z)-3-amino-4,5-(cyclohexylidenedioxy)-2-hexenoate 
• 90400-03-6 (S)-3-Acetylamino-3-((S)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-propionic acid tert-butyl ester 

Downstream Products

• 81176-33-2 N-Benzoyl-L-acosamine 
• 17016-65-8 N-benzoyl acosamine 
• 75712-53-7 (3S,4S,5S)-3-benzamido-4-hydroxy-5-hexanolide 

Relevant academic research and scientific papers

A New Synthesis of 3-Amino-2-alkenoates. Novel Synthetic Route to Amino Sugars N-benzoyl-L-daunosamine and -L-acosamine

Alkanoate esters are found to couple with various nitriles to give (Z)-3-amino-2-alkenoates in good yields with the aid of a magnesium amide prepared by the reaction of ethylmagnesium bromide and diisopropylamine.The C-C bond forming reaction was applied

Synthesis of N-Trifluoroacetyl-L-acosamine and -L-daunosamine

N-Trifluoroacetyl-L-acosamine (18) has been chirally synthesised from the chiral educt (1) obtained from cinnamaldehyde and bakers' yeast, whereas N-trifluoroacetyl-L-daunosamine (17) was obtained by inverting the configuration at C-4 of the intermediate