7576-36-5

Upstream product

• 6832-16-2 methyl diazoacetate 
• 501-65-5 diphenyl acetylene 
• 235092-63-4 3-Methoxycarbonyl-1,2-diphenyl-3-trimethylsilylcyclopropene 
• 150017-32-6 1-Azido-2,3-diphenyl-cycloprop-2-enecarboxylic acid ethyl ester 
• 150017-29-1 2,3-Dibromo-2,3-diphenyl-cyclopropanecarboxylic acid ethyl ester 
• 7382-06-1 ethyl 2,3-diphenylcycloprop-2-enecarboxylate 
• 100-52-7 benzaldehyde 
• 77817-10-8 methyl 2,3-dichloro-cis,cis-2,3-diphenylcyclopropanecarboxylate 

Downstream Products

• 109399-55-5 tert-butyl 2,3-diphenylcycloprop-2-ene-1-carboxylate 
• 104124-51-8 methyl 2-chloromercurio-3-acetoxy-2,3-diphenylcyclopropane-1-carboxylate 
• 104124-50-7 2-chloromercuri-3-trifluoroacetoxy-2,3-diphenylcyclopropane-1-carboxylic methyl ester 
• 110574-31-7 methyl 3-(1-methoxycarbonyl-2,3-diphenylcyclopropyl)-2,3-diphenylcyclopropene-1-carboxylate 
• 110574-31-7 methyl 3-(1-methoxycarbonyl-2,3-diphenylcyclopropyl)-2,3-diphenylcyclopropene-1-carboxylate 
• 40814-92-4 dimethyl 1,2,4,5-tetraphenyltricyclo<3.1.0.0^2,4>-hexane-3,6-dicarboxylate 
• 40814-92-4 dimethyl 1,2,4,5-tetraphenyltricyclo<3.1.0.0^2,4>-hexane-3,6-dicarboxylate 
• 103363-90-2 2-methoxy-4,5-diphenylfuran 
• 110574-32-8 methyl 2,2,3,3-tetramethyl-1,4-diphenylbicyclo<2.1.0>pentane-5-carboxylate 
• 64162-51-2 methyl 2,3-diphenylcyclopropenecarboxylate 
• 77060-83-4 methyl t,t-2,3-diphenyl-c-2-formylcyclopropane-r-1-carboxylate 
• 7381-97-7 methyl ester of 2β,3β-diphenylcyclopropane-1α-carboxylic acid 
• 5682-62-2 allcis-2.3-Diphenyl-cyclopropan-1-carbonsaeuremethylester 
• 5682-62-2 methyl ester of (racemic) 2,3-diphenylcyclopropane-1-carboxylic acid 

Relevant academic research and scientific papers

Synthesis of Diazanorcaradienes and 1,2-Diazepines via the Tandem [4+2]-Cycloaddition/Retro-[4+2]-Cycloaddition Reaction between Methoxycarbonylcyclopropenes and Dimethoxycarbonyltetrazine

The reaction of di(methoxycarbonyl)tetrazine with substituted cycloprop-2-ene-1-carboxylates gives a series of 3,4-diazanorcaradienes and 1,2-diazepines. The influence of the nature of cyclopropenes and the reaction conditions on its selectivity was inves

Synthesis of 3-aryl-3-trimethylsilylcyclopropenes and their dibenzoyl derivatives. Possible cyclopropenyl anion precursors?

3-Aryl-3-trimethylsilylcyclopropenes (1) were synthesized by a four-step reaction sequence starting from known benzoyl trimethylsilanes. These cyclopropenes were thermalized on a gas chromatography column and the products were collected and identified. Their 1, 2-dibenzoyl derivatives (2) were prepared in a two-step transformation beginning with 3-aryl-1, 2, 3-tris(trimethylsilyl)cyclopropenes (5), the ultimate intermediates in the syntheses of 1. These compounds (2) are rare examples of isolable cyclopropenes with electron withdrawing groups at the vinyl positions. Fluoride-induced desilylation reactions of electron deficient cyclopropenes also are described and a carbon-centered electrophile has been successfully used to trap a putative cyclopropenyl anion.

1,2,3-Triazines, IV. - Synthesis of 1,2,3-Triazinecarboxylates

1,2,3-Triazinecarboxylates 5 have been prepared by rearrangement of the cyclopropenyl azides 6 as well as by oxidation of the 1-aminopyrazoles 9, 10.Reaction of 1-aminopyrazole-5-carboxylates 10 with triethyl orthoformate (19) and ammonia affords pyrazolotriazin-4-ones 18 Key Words: 1,2,3-Triazines / Cyclopropenyl azides / Pyrazoles / Pyrazolotriazines

STEREOCHEMISTRY OF THE ADDITION OF CHLORINE TO METHYL 2,3-DIPHENYL-2-CYCLOPROPENECARBOXYLATE

The reaction of chlorine with methyl 2,3-diphenyl-2-cyclopropenecarboxylate was investigated.The addition of chlorine to the cyclopropene double bond takes place stereospecifically at the cis position.The structure and configuration of the obtained methyl