77060-83-4Relevant academic research and scientific papers
RADICAL HYDROFORMYLATION AND HYDROGENATION OF CYCLOPROPENES WITH HCo(CO)4 AND HMn(CO)5
Nalesnik, Theodore E.,Freudenberger, John H,,Orchin, Milton
, p. 95 - 100 (2007/10/02)
The results of a study of the reactions of HCo(CO)4 and HMn(CO)5 with a variety of substituted cyclopropenes are consistent with the formation of intermediate caged radical pairs; recombination in the cage of the radical pair leads to hydroformylation, an
Reaction of HCo(CO)4 with Methyl 2,3-Diphenyl-2-cyclopropene-1-carboxylate: Synthesis of Methyl t,t-2,3-Diphenyl-c-2-formylcyclopropane-r-1-carboxylate
Nalesnik, Theodore E.,Fish, John G.,Horgan, Steven W.,Orchin, Milton
, p. 1987 - 1990 (2007/10/02)
Reaction of HCo(CO)4 with the diphenylcyclopropene 1 leads to the three possible hydrogenated cyclopropanes but in addition a single hydroformylation product is formed.This aldehyde was synthesized by an unambiguous procedure; it is compound 2, formed by
