75765-67-2Relevant academic research and scientific papers
New aspects on the reactivity of radicals generated from 5′-deoxy-5′-iodoadenosine derivatives
Maria, Edmilson Jose,Fourrey, Jean-Louis,Machado, Antonio S.,Robert-Gero, Malka
, p. 27 - 33 (1996)
Acrylonitrile can serve as a trap for a 5′-centered radical derived from adenosine affording the corresponding three carbon extended adenosine derivative 8 together with the known 5′,8-cyclization product 9.
SYNTHESE DE LA CYCLO-5'-8 DESOXY-5' ADENOSINE: STEREOCHIMIE ET MECHANISME DE LA CYCLISATION D'UN DERIVE DE L'IODO-5' ADENOSINE PAR LE ZINC
Zylber, J.,Pontikis, R.,Merrien, A.,Merienne, C.,Baran-Marszak, M.,Gaudemer, A.
, p. 1579 - 1584 (2007/10/02)
N,N'-Dibenzoyl 2',3'-O-isopropylidene 5'-deoxy 5'-iodo adenosine can efficiently transformed into the corresponding 5',8-cyclo-7,8-dihydronucleoside by zinc in pyridine.Only one diastereoisomer is obtained.By spin decoupling and NOE techniques at 250 MHz,
