75819-53-3Relevant academic research and scientific papers
Strain-Modulated Reactivity: An Acidic Silane
Tretiakov, Serhii,Witteman, Léon,Lutz, Martin,Moret, Marc-Etienne
supporting information, p. 9618 - 9626 (2021/03/19)
Compounds of main-group elements such as silicon are attractive candidates for green and inexpensive catalysts. For them to compete with state-of-the-art transition-metal complexes, new reactivity modes must be unlocked and controlled, which can be achiev
Photochemistry of 1-Azatriptycene
Sugawara, Tadashi,Iwamura, Hiizu
, p. 1329 - 1339 (2007/10/02)
1-Azatriptycene (1) underwent photorearrangement in basic methanol with a quantum efficiency of 0.57 to give 4H-azepine derivative (4) as the main product.In the presence of TCNE, the Diels-Alder adduct (5) of the 1H-azepine intermediate was obtained.In a
Low-Temperature and Time-Resolved Absorption Spectral Studies on the sp- and ap-2-(9-Fluorenyl)phenylnitrenes Generated from 1-Azatriptycene and 2-(9-Fluorenyl)phenyl Azide
Sugawara, Tadashi,Nakashima, Nobuaki,Yoshihara, Keitaro,Iwamura, Hiizu
, p. 858 - 862 (2007/10/02)
Mechanistic details of the photorearrangement of 1-azatriptycene (1) have been disclosed by absorption spectroscopic studies on the irradiation of 1 and o- and p-(9-fluorenyl)phenyl azides (3 and 4).At 77 K, 1 developed on irradiation absorption peaks at
